General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 4.5, Problem 4.18P
What is the shape around the indicated atom in each molecule? Don’t forget to draw in all needed Ione pairs before determining molecular shape.
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Pick the approximate bond angle indicated of the molecule with the Lewis structure below. All atoms except H have an octet of electrons. Lone pairs are not indicated.
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Chapter 4 Solutions
General, Organic, & Biological Chemistry
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.5PCh. 4.1 - Draw a Lewis structure for each covalent molecule....Ch. 4.1 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.8PCh. 4.2 - Prob. 4.9PCh. 4.2 - Prob. 4.10P
Ch. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.4 - Prob. 4.13PCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.17PCh. 4.5 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.20PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.7 - Prob. 4.23PCh. 4.8 - Prob. 4.24PCh. 4.9 - Prob. 4.25PCh. 4.9 - Prob. 4.26PCh. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 4.29PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 4.31PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 4.33PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 4.51PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.59PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 4.61PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.63PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 4.83PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 4.89PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Prob. 4.93PCh. 4 - Prob. 4.94PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 4.96PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 4.98CPCh. 4 - Prob. 4.99CPCh. 4 - Prob. 4.100CP
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- Helparrow_forwardPart E: Polarity of Molecules After watching the video on Polarity of Molecules, determine if the entire molecule for each structure shown below is polar or nonpolar. In addition, be sure to indicate polar bonds using arrows or partial charge (delta ō signs) as shown in the first example. Remember, a C-H bond is nonpolar and nonpolar bonds would not require an arrow in this process. 3D Sketch of Molecule Polar or Nonpolar? Formula Molecular Geometry Tetrahedral &- CH2Cl2 Polar CH3CI Tetrahedral CI H. CC14 Tetrahedral CI Co Cl CI CI NH3 Trigonal pyramidal H. H. SO2 Bent CO2 Linear 180° 0=C=0 H2CO Trigonal planar H. H.arrow_forwardQuestion: For each molecule, draw its shape using Lewis structures and VSEPR theory. Include your steps in creating each sketch. Each diagram should include labelled electronegativities and partial charges for each atom within the molecule, and vector arrows representing the magnitude and direction of each bond dipole and net dipole (for polar molecules). Finally, determine whether the molecule is polar or non-polar and explain your rationale based on bond polarity and molecular shape. CH2Cl2 NI3 CH2O BeF2 SF6 SO2 HBrarrow_forward
- Part A For each formula, fill in the eight items listed in the instructions. The Lewis models (at least) should be completed before coming to lab. Be sure to consider the Lewis dot model and the ball-and-stick model as two separate items. The Lewis model should not attempt to indicate geometry. The ball-and-stick model does not need to show multiple bonds or the positions of lone pairs of electrons but should depict molecular geometry. Since ions have a net charge, the issue of polarity is usually unimportant for them. You can skip the polarity analysis for the ions. Fill in the all blanks!arrow_forwardAnswer the following question.arrow_forward1. Draw the best Lewis dot structure for the anion CCI3 in the correct molecular geometry [Include formal charges and lone pair electrons, and use dashed and solid wedge bonds if necessary] 2. How many electron groups are present around the central atom and what is the electron group geometry? 3. What is the molecular geometry and ideal bond angles? 4. Is the molecule polar or nonpolar? If it is polar, draw a dipole moment arrow next your structure to indicate the directionality of the dipole moment.arrow_forward
- 1. Draw the best Lewis dot structure for the anion CCI in the correct molecular geometry [Include formal charges and lone pair electrons, and use dashed and solid wedge bonds if necessary 2. How many electron groups are present around the central atom and what is the electron group geometry? 3. What is the molecular geometry and ideal bond angles? 4. Is the molecule polar or nonpolar? If it is polar, draw a dipole moment arrow next to your structure to indicate the directionality of the dipole moment. Answers Edit View Insert Format Tools Table 12ptv Paragaph BIVA 2 Owordh AG3454jpg IMG 3450jpgarrow_forwardWrite a Lewis structure for each of the following molecules. H2O2 Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all lone pairs of electrons.arrow_forwardWrite a Lewis structure for each of the following molecules. H2CO (carbon is central) Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all lone pairs of electrons.arrow_forward
- 1. Draw the best Lewis dot structure for the anion CCl, in the correct molecular geometry (Include formal charges and lone pair electrons, and use dashed and solid wedge bonds if necessary) 2. How many electron groups are present around the central atom and what is the electron group geometry? 3. What is the molecular geometry and ideal bond angles? 4. Is the molecule polar or honpolar? If it is polar, draw a dipole moment arrow next to your structure to indicate the directionality of the dipole moment. Answers: Edit View Insert Formuat Tools Table 12pt Paragraph BIUA 2 of Bons O words IMG4Sg IMG 3449 og IMG 344 jpg IMG 3447 jp Dearrow_forwardNO2 (minus) a) How many lone pairs (non-bounding electron pairs) does the compound possess atoms? (central atom(s) and outer atoms? b) For this compound, Identify the following -number of electron groups (electron domains) -number of atoms bounded to the central atom -number of non-bounding electron pairs (lone pairs) attached to the central atom -General formula c) What is the Electron group Geometry also called "overall shape" and Hybrid Orb =signation for the central atm? d)What is the shape the atoms make (excluding the lone pairs)? This is also called t nolecular shape"arrow_forwardXenon can be the central atom of a molecule by expanding beyond an octet of electrons. Draw Lewis structures for the given xenon compounds. Show all lone pairs. XeF2 XeF,O Rings Erase Select Draw Rings More Erase Select Draw More Xe Xe ofarrow_forward
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