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Read Appendix B on naming branched alkyl substituents, and draw all possible alkyl groups having the formula
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Chapter 4 Solutions
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- What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?arrow_forward7. Compound B is formed when an alcohol, compound A, is reacted with reagent X as shown in the equation. C4H9OH + reagant X heat → C„H£O2 compound A compound B a) (i) Identify whether compound A is a primary, secondary or tertiary alcohol, and explain your choice. (ii) Identify a reagent that could function as reagent X. But-1-ene is the only alkene produced when compound A is reacted under appropriate conditions. b) Identify the systematic name of compound B and draw its structural formula. c) Compound C, a sweet-smelling liquid, is one of two products formed when compound A reacts with compound B in the presence of a catalytic amount of sulfuric acid. Identify the systematic name of compound C and draw its structural formula.arrow_forwardCompounds with two carbonyl groups are named as alkane diones, for example: R 2,3-butanedione The compound above is an artificial flavor added to microwave popcorn and movie-theater popcorn to simulate the butter flavor. Interestingly, this very same compound is also known to contribute to body odor. Name the following compounds: cyclohexane-1,3-dione cycloheptane-1,4-dione gily nonane-2,8-dionearrow_forward
- 8. a) C3H$C1 has several structural isomers containing an alkene functional group. Complete the table by stating the systematic names and drawing the structural formulae of THREE structural isomers of C3H$Cl. Systematic Name Structural Formula b) A chemical test can be performed quickly in a school laboratory to distinguish between cyclohexanol and 1-methylcyclohexanol. Identify the reagent used in this test and describe the expected observations.arrow_forwardDraw structural formulas for these alkenes. (a) trans-2-Methyl-3-hexene (b) 2-Methyl-2-hexene (c) 2-Methyl-1-butene (d) 3-Ethyl-3-methyl-1-pentene (e) 2,3-Dimethyl-2-butene (f) cis-2-Pentene (g) (Z)-1-Chloropropene (h) 3-Methylcyclohexene (i) 1-Isopropyl-4-methylcyclohexene (j) (E)-2,6-Dimethyl-2,6-octadiene (k) 3-Cyclopropyl-1-propene (l) Cyclopropylethene (m) 2-Chloropropene (n) Tetrachloroethylene (o) 1-Chlorocyclohexenearrow_forward8 5 Alkenes are unsaturated hydrocarbons. They show structural isomerism. Alkenes take part in addition reactions and form polymers. (a) Structural isomers have the same molecular formula but different structural formulae. Give an example of structural isomerism. molecular formula . two structural formulae (b) Ethene reacts with each of the following. Give the name and structural formula of each product. (i) steam name of product structure of product (ii) hydrogen name of product structure of productarrow_forward
- Draw all possible structure(s) and give the IUPAC systematic name(s) of an alkane or cycloalkane with the formula C8H18 that has only primary hydrogen atoms. Draw the structure(s).arrow_forwardCompounds X and Y have the formula C6H12. Both X and Y react with one molar equivalent of hydrogen in the presence of a palladium catalyst to form 2-methylpentane. The heat of hydrogenation of X is less than that of Y. X and Y react with HBr to form a mixture of the same bromoalkanes, and they both undergo hydroboration/oxidation to give a mixture of the same alcohols. What is the structure of Y? • In cases where there is more than one answer, just draw one. + ChemDoodlearrow_forwardCompounds X and Y have the formula C6H₁2. Both X and Y react with one molar equivalent of hydrogen in the presence of a palladium catalyst to form 2-methylpentane. The heat of hydrogenation of X is less than that of Y. X and Y react with HBr to form a mixture of the same bromoalkanes, and they both undergo hydroboration/oxidation to give a mixture of the same alcohols. What is the structure of Y? • In cases where there is more than one answer, just draw one. MAVI Sn [F ? ChemDoodlearrow_forward
- None of the following names follow IUPAC rules (formulas are provided to reduce ambiguity): 2-oxo-4-pentanol (C5H1002) 5-propyl-4-chloro-2-hexanone (C,H17CIO) N-propylethenamine (C5H11N) Choose one of these names, explain what is wrong with it, and write the correct IUPAC name of the compound.arrow_forwardDraw the condensed structural formula or skeletal formula, if yclic, for the alkene that is the major product from each of the following dehydration reactions: H+ а. CHз— CH—— СH — СH —ОН - Heat ОН ОН b. H+ с. H+ Heat Heat ОН d. CH3— CH — CH,— СH— СH, Нeat Draw the condensed structural formula for the ether produced y each of the following reactions: H+ а. 2СH3 — ОН Heat H+ b. 2CH3 — СH>— CH-— ОН Heatarrow_forward3 Give the systematic name of the given alkene based on its semi-structural formula. CH, CH, CH, CH сн, — с %3Dсн CH CH2 - CH2 CH3 CH, Systematic name:arrow_forward
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