(a) Interpretation: The relation between the given pair of compounds is to be stated. Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

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Answer 1

Question

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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Answer 3

Question

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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Answer 4

Question

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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Answer 5

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 6

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Answer 7

Chapter 4, Problem 4.61P

Interpretation Introduction

(a)

Interpretation: The relation between the given pair of compounds is to be stated.

Concept introduction: Constitutional isomers have same molecular formula but differ in spatial arrangements of substituents. Identical isomers have same molecular formula as well as same spatial arrangements of substituents. The stereoisomers have same chemical formula but differ only in the spatial arrangement of their atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 10

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 11

Interpretation Introduction

(c)

Interpretation: The wedge-dash of B is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 12

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 13

Interpretation Introduction

(d)

Interpretation: The wedge-dash of A is to be drawn and the stereochemistry of the substituents is to be shown.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 4 - Prob. 4.1P Ch. 4 - Problem 4.2 Which of the following is not another...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Draw the five constitutional isomers that have...Ch. 4 - Problem 4.7 Give the IUPAC name for each...Ch. 4 - Give the IUPAC name for each compound. a....Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that constitutional isomers have the same molecular formula but differ in spatial arrangements of substituents.

Concept explainers

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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Chapter 4 Solutions

Solution Summary: The author explains that constitutional isomers have the same molecular formula but differ in spatial arrangements of substituents.

Concept explainers

(b) Interpretation: The given compounds are to be labeled as cis or trans isomer. Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.

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Chapter 4 Solutions

(b)

Interpretation: The given compounds are to be labeled as cis or trans isomer.

Concept introduction: Cis–trans isomers are geometrical isomers. Cis-isomer contains two groups on the same side of the ring. Trans-isomer contains two groups on the opposite side of the ring.