Draw the structure corresponding to each IUPAC name.
a.
b.
c.
d. cyclobutylcycloheptane
e.
f.
g
h.
i.
j.
(a)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Rules for writing structural formula from IUPAC are:
1. First identify the word root for the given compound.
2. The suffix used in the compound like –ene.
3. Identify the position, location, and number of the substituent bonded to the carbon chain.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Rules for writing structural formula from IUPAC are
1. First identify the word root for the given compound.
2. The suffix used in the compound like –ene.
3. Identify the position, location, and number of the substituent bonded to the carbon chain.
The given name is
Thus, the correct structure of
Figure 1
The structure corresponding to the given name is shown in Figure 1.
(b)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Rules for writing structural formula from IUPAC are:
4. First identify the word root for the given compound.
5. The suffix used in the compound like –ene.
6. Identify the position, location, and number of the substituent bonded to the carbon chain.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
The given name is
Figure 2
The structure corresponding to the given name is shown in Figure 2.
(c)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC nomenclature. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Rules for writing structural formula from IUPAC are:
1. First identify the word root for the given compound.
2. The suffix used in the compound like –ene.
3. Identify the position, location, and number of the substituent bonded to the carbon chain.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
The given name is
Thus, the correct structure of
Figure 3
The structure corresponding to the given name is shown in Figure 3.
(d)
Interpretation: The structure corresponding to cyclobutylcycloheptane is to be drawn.
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Answer to Problem 4.40P
The structure corresponding to cyclobutylcycloheptane is shown as,
Explanation of Solution
The given IUPAC name is cyclobutylcycloheptane. The given name is cyclobutylcycloheptane. The word root used in this is hept. It means structure contains seven carbon atoms. The hydrocarbons that are attached to the longest chain are called substituents and they are written as prefix in alphabetical order. Therefore, the name suggests that one cyclobutyl substituents is attached to the carbon atom of cycloheptane.
Thus, the correct structure of cyclobutylcycloheptane is shown below.
Figure 4
The structure corresponding to the given name is shown in Figure 4.
(e)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Thus, the correct structure of
Figure 5
The structure corresponding to the given name is shown in Figure 5.
(f)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Thus, the correct structure of
Figure 6
The structure corresponding to the given name is shown in Figure 6.
(g)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Thus, the correct structure of
Figure 7
The structure corresponding to the given name is shown in Figure 7.
(h)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Thus, the correct structure of
Figure 8
The structure corresponding to the given name is shown in Figure 8.
(i)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Rules for writing structural formula from IUPAC are:
4. First identify the word root for the given compound.
5. The suffix used in the compound like –ene.
6. Identify the position, location, and number of the substituent bonded to the carbon chain.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Rules for writing structural formula from IUPAC are
7. First identify the word root for the given compound.
8. The suffix used in the compound like –ene.
9. Identify the position, location, and number of the substituent bonded to the carbon chain.
The given name is
Thus, the correct structure of
Figure 9
The structure corresponding to the given name is shown in Figure 9.
(j)
Interpretation: The structure corresponding to
Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.
Rules for writing structural formula from IUPAC are:
10. First identify the word root for the given compound.
11. The suffix used in the compound like –ene.
12. Identify the position, location, and number of the substituent bonded to the carbon chain.
Answer to Problem 4.40P
The structure corresponding to
Explanation of Solution
The given IUPAC name is
Rules for writing structural formula from IUPAC are
13. First identify the word root for the given compound.
14. The suffix used in the compound like –ene.
15. Identify the position, location, and number of the substituent bonded to the carbon chain.
The given name is
Thus, the correct structure of
Figure 10
The structure corresponding to the given name is shown in Figure 10.
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