(a) Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn. Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

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Answer 1

Question

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

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Answer 3

Question

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

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Answer 4

Question

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

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Answer 5

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 6

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 7

Chapter 4, Problem 4.27P

Interpretation Introduction

(a)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given compound is to be labeled as cis or trans and then the second chair conformation is to be drawn.

Concept introduction: A cis isomer contains two substituents/groups on the same side, either both on down bonds or both on up bonds. On the other hand, a trans isomer contains two substituents/groups on the opposite sides, one down and one up.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4 - Prob. 4.1P Ch. 4 - Problem 4.2 Which of the following is not another...Ch. 4 - Problem 4.3 Draw the five constitutional isomers...Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Draw the five constitutional isomers that have...Ch. 4 - Problem 4.7 Give the IUPAC name for each...Ch. 4 - Give the IUPAC name for each compound. a....Ch. 4 - Problem 4.9 Give the structure corresponding to...Ch. 4 - Prob. 4.10P

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