The moles of Na + ions required to replace 0.015 M Ca 2 + and 0.0010 M Fe 3 + in 1.0 × 10 3 L of hard water is to be calculated. Concept introduction: Molarity ( M ) is one of the concentration terms that determine the number of moles of solute present in per liter of solution. Unit of molarity is mol/L . The expression to calculate the moles of the compound when molarity of solution and volume of solution are given is as follows: Moles of compound ( mol ) = [ volume of solution ( L ) ( molarity of solution ( mol ) 1L of solution ) ] The expression to calculate the moles of charge from an ion when moles of ion and mole of charge on ion are given is as follows: Moles of charge from ion ( mol ) = [ moles of ion ( mol ) ( mole of charge on ion ( mol ) 1 mol of ion ( mol ) ) ]
The moles of Na + ions required to replace 0.015 M Ca 2 + and 0.0010 M Fe 3 + in 1.0 × 10 3 L of hard water is to be calculated. Concept introduction: Molarity ( M ) is one of the concentration terms that determine the number of moles of solute present in per liter of solution. Unit of molarity is mol/L . The expression to calculate the moles of the compound when molarity of solution and volume of solution are given is as follows: Moles of compound ( mol ) = [ volume of solution ( L ) ( molarity of solution ( mol ) 1L of solution ) ] The expression to calculate the moles of charge from an ion when moles of ion and mole of charge on ion are given is as follows: Moles of charge from ion ( mol ) = [ moles of ion ( mol ) ( mole of charge on ion ( mol ) 1 mol of ion ( mol ) ) ]
The moles of Na+ ions required to replace 0.015M Ca2+ and 0.0010M Fe3+ in 1.0×103 L of hard water is to be calculated.
Concept introduction:
Molarity (M) is one of the concentration terms that determine the number of moles of solute present in per liter of solution. Unit of molarity is mol/L.
The expression to calculate the moles of the compound when molarity of solution and volume of solution are given is as follows:
Moles of compound(mol)=[volume of solution(L)(molarityofsolution(mol)1L of solution)]
The expression to calculate the moles of charge from an ion when moles of ion and mole of charge on ion are given is as follows:
Moles of charge from ion(mol)=[moles of ion(mol)(mole of charge on ion(mol)1mol of ion(mol))]
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
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possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
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MgBr
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CH3CH2CH2MgBr
Q10
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Q11
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2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
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Chapter 4 Solutions
Chemistry: The Molecular Nature of Matter and Change
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