The grams of ethanol that can be produced from 100 g of glucose and volume of CO 2 in the following reaction is to be calculated. C 6 H 12 O 6 ( s ) → yeast 2 C 2 H 5 OH ( l ) + 2 CO 2 ( g ) Concept introduction: Decomposition redox reactions are the reactions in which one compound decomposed to form one or more product. The reaction has at least one of the product in element form. Decomposition redox reactions can be further classified as thermal decomposition and electrolytic decomposition. In thermal decomposition, heat is employed for the decomposition reaction while in electrolytic decomposition electrical energy is employed for the decomposition reaction. The general representation of decomposition redox reaction is: Z → X + Y
The grams of ethanol that can be produced from 100 g of glucose and volume of CO 2 in the following reaction is to be calculated. C 6 H 12 O 6 ( s ) → yeast 2 C 2 H 5 OH ( l ) + 2 CO 2 ( g ) Concept introduction: Decomposition redox reactions are the reactions in which one compound decomposed to form one or more product. The reaction has at least one of the product in element form. Decomposition redox reactions can be further classified as thermal decomposition and electrolytic decomposition. In thermal decomposition, heat is employed for the decomposition reaction while in electrolytic decomposition electrical energy is employed for the decomposition reaction. The general representation of decomposition redox reaction is: Z → X + Y
Definition Definition Chemical reactions involving both oxidation and reduction processes. During a redox reaction, electron transfer takes place in such a way that one chemical compound gets reduced and the other gets oxidized.
Chapter 4, Problem 4.129P
Interpretation Introduction
Interpretation:
The grams of ethanol that can be produced from 100 g of glucose and volume of CO2 in the following reaction is to be calculated.
C6H12O6(s)→yeast2C2H5OH(l)+2CO2(g)
Concept introduction:
Decomposition redox reactions are the reactions in which one compound decomposed to form one or more product. The reaction has at least one of the product in element form. Decomposition redox reactions can be further classified as thermal decomposition and electrolytic decomposition. In thermal decomposition, heat is employed for the decomposition reaction while in electrolytic decomposition electrical energy is employed for the decomposition reaction. The general representation of decomposition redox reaction is:
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 4 Solutions
Chemistry: The Molecular Nature of Matter and Change
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