The oxidized substance and the reduced substance in step 1 and step 2 respectively is to be determined. Concept introduction: A redox reaction is a type of reaction that involves the change in oxidation number of a molecule, atom or ion changes due to the transfer of an electron from one species to another. Oxidation of a species involves the loss of electrons by that species and reduction of a species involves the gain of electrons by that species. The oxidation number is defined as the formal charge an atom would gain if all the bonds attached to it in a compound are heterolytically cleaved. Oxidation number can be a positive or negative number but cannot be fractional.
The oxidized substance and the reduced substance in step 1 and step 2 respectively is to be determined. Concept introduction: A redox reaction is a type of reaction that involves the change in oxidation number of a molecule, atom or ion changes due to the transfer of an electron from one species to another. Oxidation of a species involves the loss of electrons by that species and reduction of a species involves the gain of electrons by that species. The oxidation number is defined as the formal charge an atom would gain if all the bonds attached to it in a compound are heterolytically cleaved. Oxidation number can be a positive or negative number but cannot be fractional.
Definition Definition Chemical reactions involving both oxidation and reduction processes. During a redox reaction, electron transfer takes place in such a way that one chemical compound gets reduced and the other gets oxidized.
Chapter 4, Problem 4.142P
(a)
Interpretation Introduction
Interpretation:
The oxidized substance and the reduced substance in step 1 and step 2 respectively is to be determined.
Concept introduction:
A redox reaction is a type of reaction that involves the change in oxidation number of a molecule, atom or ion changes due to the transfer of an electron from one species to another.
Oxidation of a species involves the loss of electrons by that species and reduction of a species involves the gain of electrons by that species.
The oxidation number is defined as the formal charge an atom would gain if all the bonds attached to it in a compound are heterolytically cleaved. Oxidation number can be a positive or negative number but cannot be fractional.
(b)
Interpretation Introduction
Interpretation:
The mass of O2 that is dissolved in 50.00mL of water sample is to be determined.
Concept introduction:
Stoichiometry of a reaction is utilized to determine the amount of any species in the reaction by the relationship between the reactants and products.
Consider the general reaction,
A+2B→3C
One mole of A reacts with two moles of B to produce three moles of C. The stoichiometric ratio between A and B is 1:2, the stoichiometric ratio between A and C is 1:3 and the stoichiometric ratio between B and C is 2:3.
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
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possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
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CH3CH2CH2MgBr
Q10
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Q11
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in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
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Chapter 4 Solutions
Chemistry: The Molecular Nature of Matter and Change
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