The given ketone has to be named using IUPAC nomenclature . Concept Introduction: For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name. IUPAC rules for naming a ketone: • The longest parent carbon chain is identified that includes the carbonyl group. • The parent chain name is changed by replacing the suffix “-e” with “-one”. • Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name. • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name. • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Question

3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

Answer 1

Question

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.

1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat

3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Answer 2

Question

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 3

Question

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 4

Question

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

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Answer 5

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 6

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 7

Chapter 4, Problem 4.32EP

(a)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given ketone has to be named using IUPAC nomenclature.

Concept Introduction:

For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.

IUPAC rules for naming a ketone:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-one”.

• Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.

Answer 14

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Answer 15

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Answer 25

Ch. 4.1 - Prob. 1QQ Ch. 4.1 - Prob. 2QQ Ch. 4.2 - Prob. 1QQ Ch. 4.2 - Prob. 2QQ Ch. 4.2 - Prob. 3QQ Ch. 4.3 - Prob. 1QQ Ch. 4.3 - Prob. 2QQ Ch. 4.3 - Prob. 3QQ Ch. 4.4 - Prob. 1QQ Ch. 4.4 - Prob. 2QQ

Solution Summary: The author explains that the given ketone has to be named using IUPAC nomenclature.

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