IUPAC name for the given aldehyde has to be assigned. Concept Introduction: For naming an aldehyde in IUPAC nomenclature , the suffix “-al” is added to the parent alkane name. IUPAC rules for naming an aldehyde: • The longest parent carbon chain is identified that includes the carbonyl group. • The parent chain name is changed by replacing the suffix “-e” with “-al”. • Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1. • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name. • If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix. In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

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Answer 1

Question

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

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For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

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Answer 3

Question

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

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Answer 4

Question

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

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Answer 5

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 6

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 7

Chapter 4, Problem 4.19EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given aldehyde has to be assigned.

Concept Introduction:

For naming an aldehyde in IUPAC nomenclature, the suffix “-al” is added to the parent alkane name.

IUPAC rules for naming an aldehyde:

• The longest parent carbon chain is identified that includes the carbonyl group.

• The parent chain name is changed by replacing the suffix “-e” with “-al”.

• Numbering is done in a way that the carbonyl group is designated as number 1. This is not indicated in the part of the name because for aldehyde, the carbonyl carbon is always numbered 1.

• The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.

• If the carbonyl functional group is attached to a ring of carbon atoms, the ring is named and “-carbaldehyde” is added as suffix.

In a line-angle structural formula, the end point and the point where two lines intersect represent a carbon atom.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 4.1 - Prob. 1QQ Ch. 4.1 - Prob. 2QQ Ch. 4.2 - Prob. 1QQ Ch. 4.2 - Prob. 2QQ Ch. 4.2 - Prob. 3QQ Ch. 4.3 - Prob. 1QQ Ch. 4.3 - Prob. 2QQ Ch. 4.3 - Prob. 3QQ Ch. 4.4 - Prob. 1QQ Ch. 4.4 - Prob. 2QQ

Solution Summary: The author explains how the IUPAC name for the given aldehyde is assigned.

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Chapter 4 Solutions