Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305638686
Author: H. Stephen Stoker
Publisher: Brooks Cole
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Chapter 4, Problem 4.88EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of aldehyde or ketone that is required to prepare the given compound either by oxidation or reduction has to be given.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number CO bonds increase and/or number of CH bonds decrease.

In organic chemistry, reduction reaction is referred to the number CO bonds decrease and/or number of CH bonds increase.

Alcohols undergo oxidation reaction and reduction reaction.  This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom.  Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction.  Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product.  Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

The reverse of oxidation reaction is reduction reaction.  Reduction of aldehyde gives primary alcohol as the product and reduction of ketone gives secondary alcohol as the product.  Reduction can be accomplished using hydrogen gas and a metal catalyst namely nickel.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of aldehyde or ketone that is required to prepare the given compound either by oxidation or reduction has to be given.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number CO bonds increase and/or number of CH bonds decrease.

In organic chemistry, reduction reaction is referred to the number CO bonds decrease and/or number of CH bonds increase.

Alcohols undergo oxidation reaction and reduction reaction.  This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom.  Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction.  Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product.  Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

The reverse of oxidation reaction is reduction reaction.  Reduction of aldehyde gives primary alcohol as the product and reduction of ketone gives secondary alcohol as the product.  Reduction can be accomplished using hydrogen gas and a metal catalyst namely nickel.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of aldehyde or ketone that is required to prepare the given compound either by oxidation or reduction has to be given.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number CO bonds increase and/or number of CH bonds decrease.

In organic chemistry, reduction reaction is referred to the number CO bonds decrease and/or number of CH bonds increase.

Alcohols undergo oxidation reaction and reduction reaction.  This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom.  Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction.  Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product.  Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

The reverse of oxidation reaction is reduction reaction.  Reduction of aldehyde gives primary alcohol as the product and reduction of ketone gives secondary alcohol as the product.  Reduction can be accomplished using hydrogen gas and a metal catalyst namely nickel.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of aldehyde or ketone that is required to prepare the given compound either by oxidation or reduction has to be given.

Concept Introduction:

In organic chemistry, oxidation reaction is referred to the number CO bonds increase and/or number of CH bonds decrease.

In organic chemistry, reduction reaction is referred to the number CO bonds decrease and/or number of CH bonds increase.

Alcohols undergo oxidation reaction and reduction reaction.  This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom.  Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction.  Primary alcohols undergo oxidation to give aldehyde and carboxylic acid as product.  Secondary alcohol undergoes oxidation to give ketone as the product.

Aldehyde undergoes oxidation to give carboxylic acid as the product while ketone does not undergo oxidation reaction.

The reverse of oxidation reaction is reduction reaction.  Reduction of aldehyde gives primary alcohol as the product and reduction of ketone gives secondary alcohol as the product.  Reduction can be accomplished using hydrogen gas and a metal catalyst namely nickel.

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Chapter 4 Solutions

Organic And Biological Chemistry

Ch. 4.4 - Prob. 3QQCh. 4.4 - Prob. 4QQCh. 4.4 - Prob. 5QQCh. 4.5 - Prob. 1QQCh. 4.5 - Prob. 2QQCh. 4.5 - Prob. 3QQCh. 4.5 - Prob. 4QQCh. 4.5 - Prob. 5QQCh. 4.6 - Prob. 1QQCh. 4.6 - Prob. 2QQCh. 4.6 - Prob. 3QQCh. 4.7 - Prob. 1QQCh. 4.7 - Prob. 2QQCh. 4.8 - Prob. 1QQCh. 4.8 - Prob. 2QQCh. 4.9 - Prob. 1QQCh. 4.9 - Prob. 2QQCh. 4.10 - Prob. 1QQCh. 4.10 - Prob. 2QQCh. 4.10 - Prob. 3QQCh. 4.10 - Prob. 4QQCh. 4.11 - Prob. 1QQCh. 4.11 - Prob. 2QQCh. 4.11 - Prob. 3QQCh. 4.11 - Prob. 4QQCh. 4.11 - Prob. 5QQCh. 4.12 - Prob. 1QQCh. 4.12 - Prob. 2QQCh. 4 - Prob. 4.1EPCh. 4 - Prob. 4.2EPCh. 4 - Prob. 4.3EPCh. 4 - In terms of polarity, which carbonyl group atom...Ch. 4 - Prob. 4.5EPCh. 4 - Prob. 4.6EPCh. 4 - Prob. 4.7EPCh. 4 - Prob. 4.8EPCh. 4 - Prob. 4.9EPCh. 4 - Prob. 4.10EPCh. 4 - Prob. 4.11EPCh. 4 - Classify each of the following structures as an...Ch. 4 - Prob. 4.13EPCh. 4 - Prob. 4.14EPCh. 4 - Prob. 4.15EPCh. 4 - Prob. 4.16EPCh. 4 - Prob. 4.17EPCh. 4 - Prob. 4.18EPCh. 4 - Prob. 4.19EPCh. 4 - Prob. 4.20EPCh. 4 - Prob. 4.21EPCh. 4 - Prob. 4.22EPCh. 4 - Prob. 4.23EPCh. 4 - Prob. 4.24EPCh. 4 - Prob. 4.25EPCh. 4 - Prob. 4.26EPCh. 4 - Prob. 4.27EPCh. 4 - Prob. 4.28EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.30EPCh. 4 - Prob. 4.31EPCh. 4 - Prob. 4.32EPCh. 4 - Prob. 4.33EPCh. 4 - Prob. 4.34EPCh. 4 - Prob. 4.35EPCh. 4 - Prob. 4.36EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.38EPCh. 4 - Prob. 4.39EPCh. 4 - Prob. 4.40EPCh. 4 - Draw a structural formula for each of the...Ch. 4 - Prob. 4.42EPCh. 4 - Prob. 4.43EPCh. 4 - Name the functional group(s) present in each of...Ch. 4 - Prob. 4.45EPCh. 4 - Prob. 4.46EPCh. 4 - Prob. 4.47EPCh. 4 - Prob. 4.48EPCh. 4 - Prob. 4.49EPCh. 4 - Give IUPAC names for all saturated...Ch. 4 - Prob. 4.51EPCh. 4 - Prob. 4.52EPCh. 4 - Prob. 4.53EPCh. 4 - Prob. 4.54EPCh. 4 - Prob. 4.55EPCh. 4 - Prob. 4.56EPCh. 4 - Prob. 4.57EPCh. 4 - Prob. 4.58EPCh. 4 - Prob. 4.59EPCh. 4 - Prob. 4.60EPCh. 4 - Prob. 4.61EPCh. 4 - Prob. 4.62EPCh. 4 - Prob. 4.63EPCh. 4 - Prob. 4.64EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.66EPCh. 4 - Which member in each of the following pairs of...Ch. 4 - Prob. 4.68EPCh. 4 - Prob. 4.69EPCh. 4 - How many hydrogen bonds can form between an...Ch. 4 - Prob. 4.71EPCh. 4 - Prob. 4.72EPCh. 4 - Draw the structure of the alcohol needed to...Ch. 4 - Prob. 4.74EPCh. 4 - Prob. 4.75EPCh. 4 - Prob. 4.76EPCh. 4 - Prob. 4.77EPCh. 4 - Prob. 4.78EPCh. 4 - Prob. 4.79EPCh. 4 - Prob. 4.80EPCh. 4 - Prob. 4.81EPCh. 4 - Which of the following compounds would react with...Ch. 4 - Prob. 4.83EPCh. 4 - Prob. 4.84EPCh. 4 - Which of the three compounds pentanal,...Ch. 4 - Prob. 4.86EPCh. 4 - Prob. 4.87EPCh. 4 - Prob. 4.88EPCh. 4 - Prob. 4.89EPCh. 4 - Prob. 4.90EPCh. 4 - Prob. 4.91EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Which carbon atom is the hemiacetal carbon atom in...Ch. 4 - Prob. 4.95EPCh. 4 - Prob. 4.96EPCh. 4 - Prob. 4.97EPCh. 4 - Prob. 4.98EPCh. 4 - Prob. 4.99EPCh. 4 - Indicate whether each of the following compounds...Ch. 4 - Prob. 4.101EPCh. 4 - Prob. 4.102EPCh. 4 - Prob. 4.103EPCh. 4 - Prob. 4.104EPCh. 4 - Prob. 4.105EPCh. 4 - Prob. 4.106EPCh. 4 - Prob. 4.107EPCh. 4 - Name each of the compounds in Problem 15-106 in...Ch. 4 - Prob. 4.109EPCh. 4 - Prob. 4.110EPCh. 4 - Prob. 4.111EPCh. 4 - Prob. 4.112EPCh. 4 - Prob. 4.113EPCh. 4 - Prob. 4.114EPCh. 4 - Prob. 4.115EPCh. 4 - Prob. 4.116EPCh. 4 - Prob. 4.117EPCh. 4 - Prob. 4.118EP
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