CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Question
Chapter 4, Problem 4.20A
Interpretation Introduction
To determine:
The molarity of
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Q3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles
Considering the following reactions:
a) Predict the products to complete the reactions.
b) Use curved electron-pushing arrows to show the mechanism for the reaction in
the forward direction. Redraw some of the compounds to explicitly illustrate all
bonds that are broken and all bonds that are formed.
c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions.
A.
S
+
AICI 3
B.
+
H₂O
3. A thermometer is placed in a test tube of chipped ice at -5.0 °C. The temperature is recorded at the
time intervals shown below until room temperature is reached. Plot the data given below on graph
paper and explain all flat, horizontal portions of the curve. Plot time on the X-axis!
Time (min)
Temperature (°C)
0
-5.0
2
-2.5
4
-1.0
6
0.0
10
0.0
15
0.0
20
0.0
25
0.0
30
1.5
35
4.0
40
8.0
45
11.5
50
15.0
55
17.5
60
19.0
65
20.0
70
20.0
75
20.0
80
20.0
Naming the Alkanes
a) Write the IUPAC nomenclature of the compound below
b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and
quaternary carbons.
c) Rank pentane, neopentane and isopentane for boiling point.
pentane:
H3C-CH2-CH2-CH2-CH3
neopentane:
CH3
H3C-Ċ-CH3
I
CH3
isopentane:
CH3
H3C-CH2-CH-CH3
Chapter 4 Solutions
CHEMISTRY-TEXT
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - How many moles of solute are present in 125 mLof...Ch. 4 - Prob. 4.4ACh. 4 - Prob. 4.5PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.7PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Write ne ionic equations for the following...Ch. 4 - Prob. 4.10A
Ch. 4 - Will a precipitation reaction occur when aqueous...Ch. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Name the acids HI and HBrO2 .Ch. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Milk of magnesia (active ingredient: magnesium...Ch. 4 - Prob. 4.19PCh. 4 - Prob. 4.20ACh. 4 - Prob. 4.21PCh. 4 - Assume that the buret contains H+ ions, the flask...Ch. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Identify the oxidizing agent and reducing agent in...Ch. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Use the following reactions to arrange the...Ch. 4 - Prob. 4.29PCh. 4 - Prob. 4.30ACh. 4 - A viramin-fortified brand of a sports...Ch. 4 - The nutritional label on Power ade specifies that...Ch. 4 - Prob. 4.33PCh. 4 - One way to analyze a sports drink for the...Ch. 4 - To measure the concentration of chloride ions ina...Ch. 4 - The flavor of the first batch of Gatorade was...Ch. 4 - Prob. 4.37CPCh. 4 - Prob. 4.38CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.41CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.46SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.51SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.53SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - Prob. 4.55SPCh. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Pennies minted after 1982 are mostly zinc (97.5%)...Ch. 4 - A bottle of 12.0 M hydrochloric acid has only 35.7...Ch. 4 - What is the volume of the solution that would...Ch. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Prob. 4.61SPCh. 4 - The following aqueous solutions were tested with a...Ch. 4 - Prob. 4.63SPCh. 4 - Individual solutions of Ba(OH)2 and H2SO4 both...Ch. 4 - A solution of HCl in water conducts electricity,...Ch. 4 - Classify each of the following substances as a...Ch. 4 - Is it possible for a molecular substance to be a...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - Ringer’s solution, used in the treatment of burns...Ch. 4 - What is the molarity of each ion in a solution...Ch. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - hich of the following solutions will not form a...Ch. 4 - Which of the following solutions will not form a...Ch. 4 - How would you prepare the following substances by...Ch. 4 - How would you prepare the following substances by...Ch. 4 - What are the mass and the identity of the...Ch. 4 - What are the mass and the identity of the...Ch. 4 - Assume that you have an aqueous mixture of NaNO3...Ch. 4 - Assume that you have an aqueous mixture of BaCl2...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - How could you use a precipitation reaction to...Ch. 4 - How could you u a precipitation reaction to...Ch. 4 - The following three solutions are mixed: 100.0 mL...Ch. 4 - A 250.0 g sample of a white solid is known to be a...Ch. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Why do we use a double arrow () to show the...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - A flask containing 450 mL of 0.500 M HBr was...Ch. 4 - The odor of skunks is caused by chemical compounds...Ch. 4 - Prob. 4.102SPCh. 4 - Prob. 4.103SPCh. 4 - How many milliliters of 1.00 M KOH must be added...Ch. 4 - How many milliliters of 2.00 M HCl must be added...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - Prob. 4.108SPCh. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Nitrogen can have several different oxidation...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Neither strontium (Sr) nor antimony (Sb) is shown...Ch. 4 - (a) Use the following reactions to arrange the...Ch. 4 - Prob. 4.123SPCh. 4 - Iodine, I2 , reacts with aqueous thiosulfate ion...Ch. 4 - How many milliliters of 0.250MNa2S2O3 solution is...Ch. 4 - Dichromate ion, Cr2O72 reacts with aqueous...Ch. 4 - A volume of 18.72 mL of 0.1500MK2Cr2O7 solution...Ch. 4 - What is the molar concentration of As(III) in a...Ch. 4 - Standardized solutions of KBrO3 are frequently...Ch. 4 - The metal content of iron in ores can be...Ch. 4 - Prob. 4.131SPCh. 4 - Alcohol levels in blood can he determined by a...Ch. 4 - Calcium levels in blood can be determined by...Ch. 4 - Assume that you have 1.00 g of a mixture of...Ch. 4 - A compound with the formula XOCl2 , reacts with...Ch. 4 - Prob. 4.136MPCh. 4 - Some metals occur naturally in their elemental...Ch. 4 - A sample weighing 14.98 g and containing a small...Ch. 4 - The solubility of an ionic compound can be...Ch. 4 - Prob. 4.140MPCh. 4 - Prob. 4.141MPCh. 4 - Prob. 4.142MPCh. 4 - A sample of metal (M) reacted with both steam and...Ch. 4 - Prob. 4.144MPCh. 4 - Prob. 4.145MPCh. 4 - Iron content in ores can be determined by a redox...Ch. 4 - Prob. 4.147MPCh. 4 - Salicylic acid, used in the manufacture of...Ch. 4 - Compound X contains only the elements C, H, O, and...Ch. 4 - Prob. 4.150MPCh. 4 - Element M is prepared industrially by a two-step...Ch. 4 - Prob. 4.152MPCh. 4 - Four solutions are prepared and mixed in the...Ch. 4 - To 100.0 mL of a solution that contains 0.120MCr(...Ch. 4 - Sodium nitrite, NaNO2 , is frequently added to...Ch. 4 - Brass is an approximately 4:1 alloy of copper and...Ch. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158MP
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