Problem 4.1P Problem 4.2A Problem 4.3P: How many moles of solute are present in 125 mLof 0.20MNaHCO3 ? Problem 4.4A Problem 4.5P Problem 4.6A: APPLY 4.7 Sulfuric acid is normally purchased at a concentration of 18.0 M. How would you prepare... Problem 4.7P Problem 4.8A: Conceptual APPLY 4.9 Three different substances, A2X, A2Y, and A2Z, are dissolved in water, with the... Problem 4.9P: Write ne ionic equations for the following reaction: 2AgNO3(aq)+Na2CrO4(aq)Ag2CrO4(s)+2NaNO3(aq) Problem 4.10A Problem 4.11P: Will a precipitation reaction occur when aqueous solutions of AgClO4 and CaBr2 are mixed? If so,... Problem 4.12A: APPLY 4.13 How might you use a precipitation reaction to prepare a sample of Ca3(PO4)2? Write the... Problem 4.13P: Conceptual PRACTICE 4.14 An aqueous solution containing an anion, represented by blue spheres, is... Problem 4.14A: Conceptual APPLY 4.15 A solution containing the compounds Pb(NO3)2, KBr, and Ba(CH3CO2)2 is prepared... Problem 4.15P: Name the acids HI and HBrO2 . Problem 4.16A: APPLY 4.17 Give likely chemical formulas corresponding to the following names: (a) Phosphorous acid... Problem 4.17P: PRACTICE 4.18 Write a balanced ionic equation and net ionic equation for each of the following... Problem 4.18A: Milk of magnesia (active ingredient: magnesium hydroxide) is used as an antacid to treat indigestion... Problem 4.19P Problem 4.20A Problem 4.21P Problem 4.22A: Assume that the buret contains H+ ions, the flask contains OH ions, and each has a volume of100 mL.... Problem 4.23P: PRACTICE 4.24 Assign an oxidation number to each atom in the following compounds: (a) SnCl4 (b) CrO3... Problem 4.24A: APPLY 4.25 Chlorine can have several different oxidation numbers ranging in value from —1 to +7. (a)... Problem 4.25P: Identify the oxidizing agent and reducing agent in the reaction: 4NH3(g)+5O2(g)4NO(g)+6H2O(l) Problem 4.26A: APPLY 4.27 Police often use a Breathalyzer test to determine the ethanol (C2H5OH) content in a... Problem 4.27P: PRACTICE 4.28 Predict whether the following reactions will occur: (a) 2H+(aq)+Pt(s)H2(g)+Pt2+ (b)... Problem 4.28A: Use the following reactions to arrange the elements A, B, C, and D in order of their strength as a... Problem 4.29P Problem 4.30A Problem 4.31P: A viramin-fortified brand of a sports beveragecontains sodium chloride (NaCl), sodium citrate... Problem 4.32P: The nutritional label on Power ade specifies that there are 150 mg of sodium and 35 mg of potassium... Problem 4.33P Problem 4.34P: One way to analyze a sports drink for the concentration of chloride ions is to add silver ions and... Problem 4.35P: To measure the concentration of chloride ions ina sports beverage, an excess of silver ions were... Problem 4.36P: The flavor of the first batch of Gatorade was improved by adding lemon juice, which contains citric... Problem 4.37CP Problem 4.38CP Problem 4.39CP: Assume that an aqueous solution Of a cation, represented as a blue sphere, is allowed to mix with a... Problem 4.40CP: The following pictures represent aqueous solutions of three acids HA (A = X, Y, or Z), with... Problem 4.41CP Problem 4.42CP: The concentration of an aqueous solution of NaOCl (sodium hypochlorite; the active ingredient in... Problem 4.43CP: Assume that the electrical conductivity of a solution depends on the total concentration of... Problem 4.44CP: Based on the positions in the periodic table, which of the following reactions would you expect to... Problem 4.45CP: The following two redox reactions occur between aqueous cations and solid metals. Will a solution of... Problem 4.46SP Problem 4.47SP: How many grams of solute would you use to prepare each of the following solutions? (a) 250.0 of M... Problem 4.48SP: How many milliliters of a 0.45 M BaCl2 solution contain 15.0 g of BaCl2? Problem 4.49SP: How many milliliters of a 0.350 M KOH solution contain 0.0171 mol of KOH? Problem 4.50SP: The sterile saline solution used to rinse contact lenses can be made by dissolving 400 mg of NaCl in... Problem 4.51SP Problem 4.52SP: Copper reacts with dilute nitric acid according to the following equation:... Problem 4.53SP Problem 4.54SP: How many grams of solute would you use to prepare the following solutions? (a) 500.0 mL of 1.25 M... Problem 4.55SP Problem 4.56SP: How would you prepare 250 mL of a 0.100 M solution off luoride ions from solid CaF2 ? Specify the... Problem 4.57SP: Pennies minted after 1982 are mostly zinc (97.5%) with a copper cover. If a post-1982 penny is... Problem 4.58SP: A bottle of 12.0 M hydrochloric acid has only 35.7 mL left in it. What will the HC1 concentration be... Problem 4.59SP: What is the volume of the solution that would result by diluting 70.00 mL of 0.09 13 M NaOH to a... Problem 4.60SP: How would you prepare 250 mL of a 0.100 M solution of chloride ions from a 3.00 M stock solution of... Problem 4.61SP Problem 4.62SP: The following aqueous solutions were tested with a light bulb conductivity apparatus, as shown in... Problem 4.63SP Problem 4.64SP: Individual solutions of Ba(OH)2 and H2SO4 both conduct electricity, but the conductivity disappears... Problem 4.65SP: A solution of HCl in water conducts electricity, but a solution of HCI in chloroform, CHCl3 , does... Problem 4.66SP: Classify each of the following substances as a strong electrolyte, weak electrolyte, or non... Problem 4.67SP: Is it possible for a molecular substance to be a strong electrolyte? Explain. Problem 4.68SP: What is the total molar concentration of ions in each of the following solutions, assuming complete... Problem 4.69SP: What is the total molar concentration of ions in each of the following solutions? (a) A 1.250 M... Problem 4.70SP: Ringer’s solution, used in the treatment of burns and wounds,is prepared by dissolving 4.30 g of... Problem 4.71SP: What is the molarity of each ion in a solution prepared by dissolving 0.550 g of Na2SO4, 1.188 g of... Problem 4.72SP Problem 4.73SP Problem 4.74SP: Write net ionic equations for the reactions listed inProblem 4.72. Problem 4.75SP: Write net ionic equations for the reactions listed in Problem 4.73. Problem 4.76SP: Which of the following substances are likely to be soluble in water? (a) PbSO4(b) Ba( NO3)2 (c)... Problem 4.77SP: Which of the following substances are likely to be soluble in water? (a) ZnS(b) AU2( CO3)3 (c)... Problem 4.78SP: Predict whether a precipitation reaction will occur when aqueous solutions of the following... Problem 4.79SP: Predict whether a precipitation reaction will occur when aqueous solutions of the following... Problem 4.80SP: hich of the following solutions will not form a precipitate when added to 0.10MBaCl2 ? (a)... Problem 4.81SP: Which of the following solutions will not form a precipitate when added to 0.10 M NaOH? (a)... Problem 4.82SP: How would you prepare the following substances by a precipitation reaction? (a) PhSO4(b) Mg3( PO4)2... Problem 4.83SP: How would you prepare the following substances by a precipitation reaction? (a) Al(OH)3(b) FeS (c)... Problem 4.84SP: What are the mass and the identity of the precipitate that forms when 30.0 mL of 0.150 M HCl reacts... Problem 4.85SP: What are the mass and the identity of the precipitate that forms when 55.0 mL of 0.100MBaCI2 reacts... Problem 4.86SP: Assume that you have an aqueous mixture of NaNO3 and AgNO3 . How could you use a precipitation... Problem 4.87SP: Assume that you have an aqueous mixture of BaCl2 and CuCl2 . How could you use a precipitation... Problem 4.88SP: Assume that you have an aqueous solution of an unknown salt. Treatment of the solution with dilute... Problem 4.89SP: Assume that you have an aqueous solution of an unknown salt. Treatment of the solution with dilute... Problem 4.90SP: How could you use a precipitation reaction to separate each of the following pairs of cations? Write... Problem 4.91SP: How could you u a precipitation reaction to separate each of the following pairs of anions? Write... Problem 4.92SP: The following three solutions are mixed: 100.0 mL of 0.100MNa2SO4 , 50.0 mL of 0.300MZnCl2 , and... Problem 4.93SP: A 250.0 g sample of a white solid is known to be a mixture of KNO3,BaCl2, and NaCl. When 100.0 g of... Problem 4.94SP: Assume that you are given a solution of an unknown acid or base. How can you tell whether the... Problem 4.95SP: Why do we use a double arrow () to show the dissociation of a weak acid or weak base in aqueous... Problem 4.96SP: Write balanced ionic equations for the following reactions. (a) Aqueous perchloric acid is... Problem 4.97SP: Write balanced ionic equations for the following reactions. (a) Aqueous hydrobromic acid is... Problem 4.98SP: Write balanced net ionic equations for the following reactions. (a) LiOH(aq)+HI(aq)? (b)... Problem 4.99SP: Write balanced net ionic equations for the following reactions. Note that HClO3 is a strong acid.... Problem 4.100SP: A flask containing 450 mL of 0.500 M HBr was accidentally knocked to the floor. How many grams of... Problem 4.101SP: The odor of skunks is caused by chemical compounds called thiols. These compounds, of which... Problem 4.102SP Problem 4.103SP Problem 4.104SP: How many milliliters of 1.00 M KOH must be added to neutralize the following solutions? (a) A... Problem 4.105SP: How many milliliters of 2.00 M HCl must be added to neutralize the following solutions? (a) A mixure... Problem 4.106SP: If the following solutions are mixed, is the resulting solution acidic, basic, or neutral? (a) 50.0... Problem 4.107SP: If the following solutions are mixed, is the resulting solution acidic, basic, or neutral? (a) 65.0... Problem 4.108SP Problem 4.109SP: Assign oxidation numbers to each element in the following compounds. (a) VOCl3(b) CuSO4(c) CH2O (d)... Problem 4.110SP: Assign oxidation numbers to each element in the following ions. (a) ClO3(b) SO32(c) C2O42 (d) NO2(e)... Problem 4.111SP: Assign oxidation numbers to each element in the following ions. (a) Cr(OH)4(b) S2O32(c) NO3 (d)... Problem 4.112SP: Nitrogen can have several different oxidation numbers ranging in value from 3 to +5. (a) Write the... Problem 4.113SP Problem 4.114SP Problem 4.115SP: Where in the periodic table are the most easily reduced elements found? The most easily oxidized? Problem 4.116SP: In each of the following instances, tell whether the substance gains electrons or loses electrons in... Problem 4.117SP: Tell for each of the following substances whether the oxidation number increases or decreases in a... Problem 4.118SP: Which element is oxidized and which is reduced in each of the following reactions? (a)... Problem 4.119SP: Which element is oxidized and which is reduced in each of the following reactions? (a)... Problem 4.120SP: Use the activity series of metals (Table 4.5) to predict the outcome of each of the following... Problem 4.121SP: Neither strontium (Sr) nor antimony (Sb) is shown in the activity series of Table 4.5. Based on... Problem 4.122SP: (a) Use the following reactions to arrange the elements A, B, C,and D in order of their decreasing... Problem 4.123SP Problem 4.124SP: Iodine, I2 , reacts with aqueous thiosulfate ion in neutral solution according to the balanced... Problem 4.125SP: How many milliliters of 0.250MNa2S2O3 solution is needed for complete reaction with 2.486 g of I2... Problem 4.126SP: Dichromate ion, Cr2O72 reacts with aqueous iron(II) ion in acidic solution according to the balanced... Problem 4.127SP: A volume of 18.72 mL of 0.1500MK2Cr2O7 solution was required to titrate a sample of FeSO4 according... Problem 4.128SP: What is the molar concentration of As(III) in a solution if22.35 mL of 0.100MKBrO3 is needed for... Problem 4.129SP: Standardized solutions of KBrO3 are frequently used inredox titrations. The necessary solution can... Problem 4.130SP: The metal content of iron in ores can be determined by aredox procedure in which the sample is first... Problem 4.131SP Problem 4.132SP: Alcohol levels in blood can he determined by a redox reaction with potassium dichromate according to... Problem 4.133SP: Calcium levels in blood can be determined by adding oxalate ion to precipitate calcium oxalate,... Problem 4.134MP: Assume that you have 1.00 g of a mixture of benzoic acid (Mol.wt.=122) and gallic acid (Mol.wt.=170)... Problem 4.135MP: A compound with the formula XOCl2 , reacts with water,yielding HCI and another acid H2XO3 , which... Problem 4.136MP Problem 4.137MP: Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold... Problem 4.138MP: A sample weighing 14.98 g and containing a small amount of copper was treated to give a solution... Problem 4.139MP: The solubility of an ionic compound can be described quantitatively by a value called the solubility... Problem 4.140MP Problem 4.141MP Problem 4.142MP Problem 4.143MP: A sample of metal (M) reacted with both steam and aqueousHCI to release H2 but did not react with... Problem 4.144MP Problem 4.145MP Problem 4.146MP: Iron content in ores can be determined by a redox procedure in which the sample is first reduced... Problem 4.147MP Problem 4.148MP: Salicylic acid, used in the manufacture of aspirin, contains only the elements C, H, and O and has... Problem 4.149MP: Compound X contains only the elements C, H, O, and S. A5.00 g sample undergoes complete combustion... Problem 4.150MP Problem 4.151MP: Element M is prepared industrially by a two-step procedure according to the following (unbalanced)... Problem 4.152MP Problem 4.153MP: Four solutions are prepared and mixed in the following order: (a) Start with 100.0 mL of 0.100MBaCI2... Problem 4.154MP: To 100.0 mL of a solution that contains 0.120MCr( NO3)2 and 0.500MHNO3 is added to 20.0 mL of... Problem 4.155MP: Sodium nitrite, NaNO2 , is frequently added to processed meats as a preservative. The amount of... Problem 4.156MP: Brass is an approximately 4:1 alloy of copper and zinc, along with small amounts of tin, lead, and... Problem 4.157MP Problem 4.158MP format_list_bulleted