Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Textbook Question
Chapter 3.8, Problem 3.18PSP
Assume the methanol synthesis has an 85.0% yield and you want to make 1.00 kg CH3OH. Calculate the mass (g) of H2 you should use if you have sufficient CO.
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Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.
This organic molecule is dissolved in an acidic aqueous solution:
OH
OH
A short time later sensitive infrared spectroscopy reveals the presence of a new C = O stretch absorption. That is, there must now be a new molecule present
with at least one C = O bond.
In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule.
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Problem 19 of 48
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Curved arrows are used to
illustrate the flow of electrons.
Use the reaction conditions
provided and follow the curved
arrows to draw the product of
this carbocation rearrangement.
Include all lone pairs and
charges as appropriate.
H
1,2-alkyl shift
+
Chapter 3 Solutions
Chemistry: The Molecular Science
Ch. 3.1 - When washing soda, Na2CO3, reacts with sulfuric...Ch. 3.2 - When sprayed into the flame of a torch, powdered...Ch. 3.2 - Prob. 3.1PSPCh. 3.2 - Prob. 3.2PSPCh. 3.3 - Prob. 3.3PSPCh. 3.3 - Prob. 3.4PSPCh. 3.3 - Prob. 3.5PSPCh. 3.3 - Prob. 3.6PSPCh. 3.3 - Prob. 3.3CECh. 3.4 - Phosphoric acid, H3PO4, has three protons that can...
Ch. 3.4 - Prob. 3.5CECh. 3.4 - Look back through the discussion of electrolytes...Ch. 3.4 - Prob. 3.8PSPCh. 3.4 - Prob. 3.9PSPCh. 3.4 - Write a balanced equation for the reaction of...Ch. 3.4 - Prob. 3.6ECh. 3.4 - Prob. 3.7ECh. 3.4 - Prob. 3.8ECh. 3.4 - Prob. 3.9CECh. 3.4 - Prob. 3.10CECh. 3.5 - Prob. 3.11CECh. 3.5 - Prob. 3.12CECh. 3.5 - Prob. 3.13ECh. 3.5 - Prob. 3.11PSPCh. 3.5 - Prob. 3.12PSPCh. 3.5 - Prob. 3.14CECh. 3.6 - Prob. 3.15CECh. 3.6 - Prob. 3.16ECh. 3.6 - Prob. 3.13PSPCh. 3.6 - Prob. 3.17ECh. 3.6 - Prob. 3.14PSPCh. 3.7 - Prob. 3.15PSPCh. 3.7 - Using the same reaction, calculate the mass of...Ch. 3.7 - At high temperatures, silicon dioxide reacts with...Ch. 3.7 - Urea is used as a fertilizer because it can react...Ch. 3.8 - Assume the methanol synthesis has an 85.0% yield...Ch. 3.8 - Prob. 3.19PSPCh. 3.8 - Prob. 3.19ECh. 3.8 - Prob. 3.20ECh. 3.9 - Phenol is a compound of carbon, hydrogen, and...Ch. 3.9 - Calcium carbonate forms carbon dioxide and calcium...Ch. 3.10 - Prob. 3.20PSPCh. 3.10 - Prob. 3.23ECh. 3.10 - Prob. 3.24ECh. 3.10 - Prob. 3.25CECh. 3.10 - Describe how you would prepare each solution.
1.00...Ch. 3.10 - Prob. 3.26ECh. 3.10 - Prob. 3.22PSPCh. 3.10 - Prob. 3.27CECh. 3.11 - Prob. 3.23PSPCh. 3.11 - Prob. 3.24PSPCh. 3.11 - Sodium chloride is used in intravenous solutions...Ch. 3.12 - Show that the reaction of KMnO4 with H2O2 is a...Ch. 3.12 - Prob. 3.25PSPCh. 3 - Aqueous solutions of ammonium sulfide and...Ch. 3 - In a blast furnace at high temperature, iron(III)...Ch. 3 - What information does a balanced chemical equation...Ch. 3 - Prob. 2QRTCh. 3 - Prob. 3QRTCh. 3 - Prob. 4QRTCh. 3 - Prob. 5QRTCh. 3 - Prob. 6QRTCh. 3 - When asked, “What is the limiting reactant?” you...Ch. 3 - Prob. 8QRTCh. 3 - Prob. 9QRTCh. 3 - For this reaction, fill in the table with the...Ch. 3 - Prob. 11QRTCh. 3 - Prob. 12QRTCh. 3 - This diagram shows A (blue spheres) reacting with...Ch. 3 - Prob. 14QRTCh. 3 - Prob. 15QRTCh. 3 - Prob. 16QRTCh. 3 - Prob. 17QRTCh. 3 - Prob. 18QRTCh. 3 - Prob. 19QRTCh. 3 - Balance these equations. (a) UO2(s) + HF() UF4(s)...Ch. 3 - Prob. 21QRTCh. 3 - Prob. 22QRTCh. 3 - Prob. 23QRTCh. 3 - Balance these combustion reactions. (a) C6H12O6 +...Ch. 3 - Prob. 25QRTCh. 3 - Prob. 26QRTCh. 3 - Prob. 27QRTCh. 3 - Which substance conducts electricity when...Ch. 3 - Prob. 29QRTCh. 3 - Predict whether each compound is soluble in water....Ch. 3 - Prob. 31QRTCh. 3 - Which drawing is the best nanoscale representation...Ch. 3 - If aqueous solutions of potassium carbonate and...Ch. 3 - If aqueous solutions of potassium sulfide and...Ch. 3 - Prob. 35QRTCh. 3 - Prob. 36QRTCh. 3 - Prob. 37QRTCh. 3 - Prob. 38QRTCh. 3 - Prob. 39QRTCh. 3 - Prob. 40QRTCh. 3 - Prob. 41QRTCh. 3 - Prob. 42QRTCh. 3 - Prob. 43QRTCh. 3 - Prob. 44QRTCh. 3 - Prob. 45QRTCh. 3 - Prob. 46QRTCh. 3 - Prob. 47QRTCh. 3 - Prob. 48QRTCh. 3 - Prob. 49QRTCh. 3 - Prob. 50QRTCh. 3 - Prob. 51QRTCh. 3 - Prob. 52QRTCh. 3 - Prob. 53QRTCh. 3 - Prob. 54QRTCh. 3 - Prob. 55QRTCh. 3 - Prob. 56QRTCh. 3 - Prob. 57QRTCh. 3 - Prob. 58QRTCh. 3 - Nitrogen monoxide is oxidized in air to give brown...Ch. 3 - Prob. 60QRTCh. 3 - The final step in the manufacture of platinum...Ch. 3 - Disulfur dichloride, S2Cl2, is used to vulcanize...Ch. 3 - Prob. 63QRTCh. 3 - Prob. 64QRTCh. 3 - Prob. 65QRTCh. 3 - Prob. 66QRTCh. 3 - Prob. 67QRTCh. 3 - Cisplatin, Pt(NH3)2Cl2, a drug used in the...Ch. 3 - Aluminum chloride, Al2Cl6, is an inexpensive...Ch. 3 - Prob. 70QRTCh. 3 - Prob. 71QRTCh. 3 - Prob. 72QRTCh. 3 - Prob. 73QRTCh. 3 - Quicklime, CaO, is formed when calcium hydroxide...Ch. 3 - Prob. 75QRTCh. 3 - Disulfur dichloride, which has a revolting smell,...Ch. 3 - Prob. 77QRTCh. 3 - Prob. 78QRTCh. 3 - Quinone, which is used in the dye industry and in...Ch. 3 - l-Dopa is a drug used for the treatment of...Ch. 3 - Write the balanced chemical equation for the...Ch. 3 - Prob. 82QRTCh. 3 - Prob. 83QRTCh. 3 - Prob. 84QRTCh. 3 - Prob. 85QRTCh. 3 - Prob. 86QRTCh. 3 - You need 300. mL of 0.500-M K2Cr2O7. Which method...Ch. 3 - You need to make a 0.300-M solution of NiSO4(aq)....Ch. 3 - You wish to make a 0.200-M solution of CuSO4(aq)....Ch. 3 - Prob. 90QRTCh. 3 - Prob. 91QRTCh. 3 - You mix 25.0 mL of 0.234-M FeCl3 solution with...Ch. 3 - A soft drink contains an unknown mass of citric...Ch. 3 - Prob. 94QRTCh. 3 - Prob. 95QRTCh. 3 - Potassium hydrogen phthalate, KHC8H4O4, is used to...Ch. 3 - Prob. 97QRTCh. 3 - Prob. 98QRTCh. 3 - Prob. 99QRTCh. 3 - Prob. 100QRTCh. 3 - Boron forms an extensive series of compounds with...Ch. 3 - Prob. 102QRTCh. 3 - Prob. 103QRTCh. 3 - Prob. 104QRTCh. 3 - Prob. 105QRTCh. 3 - Azurite is a copper-containing mineral that often...Ch. 3 - Prob. 107QRTCh. 3 - Prob. 108QRTCh. 3 - Vitamin C is ascorbic acid, HC6H7O6, which can be...Ch. 3 - Prob. 110QRTCh. 3 - Prob. 111QRTCh. 3 - Prob. 112QRTCh. 3 - Prob. 113QRTCh. 3 - Prob. 114QRTCh. 3 - Prob. 115QRTCh. 3 - Prob. 116QRTCh. 3 - Prob. 117QRTCh. 3 - Prob. 118QRTCh. 3 - Prob. 119QRTCh. 3 - Prob. 120QRTCh. 3 - Ammonia can be formed by a direct reaction of...Ch. 3 - Carbon monoxide burns readily in oxygen to form...Ch. 3 - Prob. 123QRTCh. 3 - Write a balanced chemical equation that represents...Ch. 3 - A student set up an experiment for six different...Ch. 3 - A weighed sample of a metal is added to liquid...Ch. 3 - Prob. 127QRTCh. 3 - Prob. 128QRTCh. 3 - Each box represents a tiny volume in an aqueous...Ch. 3 - Consider the chemical reaction 2 S + 3 O2 → 2 SO3....Ch. 3 - Prob. 131QRTCh. 3 - Prob. 132QRTCh. 3 - Prob. 133QRTCh. 3 - Prob. 134QRTCh. 3 - Prob. 135QRTCh. 3 - Prob. 136QRTCh. 3 - Prob. 137QRTCh. 3 - Prob. 138QRTCh. 3 - Prob. 139QRTCh. 3 - Prob. 140QRTCh. 3 - Prob. 141QRTCh. 3 - Prob. 142QRTCh. 3 - In a reaction, 1.2 g element A reacts with exactly...Ch. 3 - Prob. 144QRTCh. 3 - When solutions of silver nitrate and sodium...Ch. 3 - Nickel metal reacts with aqueous silver nitrate in...Ch. 3 - Prob. 147QRTCh. 3 - Prob. 148QRTCh. 3 - Prob. 149QRTCh. 3 - Prob. 150QRTCh. 3 - A mountain lake that is 4.0 km × 6.0 km with an...Ch. 3 - Prob. 152QRTCh. 3 - Prob. 153QRTCh. 3 - Prob. 154QRTCh. 3 - Prob. 155QRTCh. 3 - Ethanol, C2H5OH, is a gasoline additive that can...Ch. 3 - Prob. 157QRTCh. 3 - Prob. 3.ACPCh. 3 - Prob. 3.BCPCh. 3 - Prob. 3.DCPCh. 3 - Prob. 3.ECPCh. 3 - Prob. 3.FCPCh. 3 - Prob. 3.GCP
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