
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Textbook Question
Chapter 3.8, Problem 3.18PSP
Assume the methanol synthesis has an 85.0% yield and you want to make 1.00 kg CH3OH. Calculate the mass (g) of H2 you should use if you have sufficient CO.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
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2
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NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
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a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 3 Solutions
Chemistry: The Molecular Science
Ch. 3.1 - When washing soda, Na2CO3, reacts with sulfuric...Ch. 3.2 - When sprayed into the flame of a torch, powdered...Ch. 3.2 - Prob. 3.1PSPCh. 3.2 - Prob. 3.2PSPCh. 3.3 - Prob. 3.3PSPCh. 3.3 - Prob. 3.4PSPCh. 3.3 - Prob. 3.5PSPCh. 3.3 - Prob. 3.6PSPCh. 3.3 - Prob. 3.3CECh. 3.4 - Phosphoric acid, H3PO4, has three protons that can...
Ch. 3.4 - Prob. 3.5CECh. 3.4 - Look back through the discussion of electrolytes...Ch. 3.4 - Prob. 3.8PSPCh. 3.4 - Prob. 3.9PSPCh. 3.4 - Write a balanced equation for the reaction of...Ch. 3.4 - Prob. 3.6ECh. 3.4 - Prob. 3.7ECh. 3.4 - Prob. 3.8ECh. 3.4 - Prob. 3.9CECh. 3.4 - Prob. 3.10CECh. 3.5 - Prob. 3.11CECh. 3.5 - Prob. 3.12CECh. 3.5 - Prob. 3.13ECh. 3.5 - Prob. 3.11PSPCh. 3.5 - Prob. 3.12PSPCh. 3.5 - Prob. 3.14CECh. 3.6 - Prob. 3.15CECh. 3.6 - Prob. 3.16ECh. 3.6 - Prob. 3.13PSPCh. 3.6 - Prob. 3.17ECh. 3.6 - Prob. 3.14PSPCh. 3.7 - Prob. 3.15PSPCh. 3.7 - Using the same reaction, calculate the mass of...Ch. 3.7 - At high temperatures, silicon dioxide reacts with...Ch. 3.7 - Urea is used as a fertilizer because it can react...Ch. 3.8 - Assume the methanol synthesis has an 85.0% yield...Ch. 3.8 - Prob. 3.19PSPCh. 3.8 - Prob. 3.19ECh. 3.8 - Prob. 3.20ECh. 3.9 - Phenol is a compound of carbon, hydrogen, and...Ch. 3.9 - Calcium carbonate forms carbon dioxide and calcium...Ch. 3.10 - Prob. 3.20PSPCh. 3.10 - Prob. 3.23ECh. 3.10 - Prob. 3.24ECh. 3.10 - Prob. 3.25CECh. 3.10 - Describe how you would prepare each solution.
1.00...Ch. 3.10 - Prob. 3.26ECh. 3.10 - Prob. 3.22PSPCh. 3.10 - Prob. 3.27CECh. 3.11 - Prob. 3.23PSPCh. 3.11 - Prob. 3.24PSPCh. 3.11 - Sodium chloride is used in intravenous solutions...Ch. 3.12 - Show that the reaction of KMnO4 with H2O2 is a...Ch. 3.12 - Prob. 3.25PSPCh. 3 - Aqueous solutions of ammonium sulfide and...Ch. 3 - In a blast furnace at high temperature, iron(III)...Ch. 3 - What information does a balanced chemical equation...Ch. 3 - Prob. 2QRTCh. 3 - Prob. 3QRTCh. 3 - Prob. 4QRTCh. 3 - Prob. 5QRTCh. 3 - Prob. 6QRTCh. 3 - When asked, “What is the limiting reactant?” you...Ch. 3 - Prob. 8QRTCh. 3 - Prob. 9QRTCh. 3 - For this reaction, fill in the table with the...Ch. 3 - Prob. 11QRTCh. 3 - Prob. 12QRTCh. 3 - This diagram shows A (blue spheres) reacting with...Ch. 3 - Prob. 14QRTCh. 3 - Prob. 15QRTCh. 3 - Prob. 16QRTCh. 3 - Prob. 17QRTCh. 3 - Prob. 18QRTCh. 3 - Prob. 19QRTCh. 3 - Balance these equations. (a) UO2(s) + HF() UF4(s)...Ch. 3 - Prob. 21QRTCh. 3 - Prob. 22QRTCh. 3 - Prob. 23QRTCh. 3 - Balance these combustion reactions. (a) C6H12O6 +...Ch. 3 - Prob. 25QRTCh. 3 - Prob. 26QRTCh. 3 - Prob. 27QRTCh. 3 - Which substance conducts electricity when...Ch. 3 - Prob. 29QRTCh. 3 - Predict whether each compound is soluble in water....Ch. 3 - Prob. 31QRTCh. 3 - Which drawing is the best nanoscale representation...Ch. 3 - If aqueous solutions of potassium carbonate and...Ch. 3 - If aqueous solutions of potassium sulfide and...Ch. 3 - Prob. 35QRTCh. 3 - Prob. 36QRTCh. 3 - Prob. 37QRTCh. 3 - Prob. 38QRTCh. 3 - Prob. 39QRTCh. 3 - Prob. 40QRTCh. 3 - Prob. 41QRTCh. 3 - Prob. 42QRTCh. 3 - Prob. 43QRTCh. 3 - Prob. 44QRTCh. 3 - Prob. 45QRTCh. 3 - Prob. 46QRTCh. 3 - Prob. 47QRTCh. 3 - Prob. 48QRTCh. 3 - Prob. 49QRTCh. 3 - Prob. 50QRTCh. 3 - Prob. 51QRTCh. 3 - Prob. 52QRTCh. 3 - Prob. 53QRTCh. 3 - Prob. 54QRTCh. 3 - Prob. 55QRTCh. 3 - Prob. 56QRTCh. 3 - Prob. 57QRTCh. 3 - Prob. 58QRTCh. 3 - Nitrogen monoxide is oxidized in air to give brown...Ch. 3 - Prob. 60QRTCh. 3 - The final step in the manufacture of platinum...Ch. 3 - Disulfur dichloride, S2Cl2, is used to vulcanize...Ch. 3 - Prob. 63QRTCh. 3 - Prob. 64QRTCh. 3 - Prob. 65QRTCh. 3 - Prob. 66QRTCh. 3 - Prob. 67QRTCh. 3 - Cisplatin, Pt(NH3)2Cl2, a drug used in the...Ch. 3 - Aluminum chloride, Al2Cl6, is an inexpensive...Ch. 3 - Prob. 70QRTCh. 3 - Prob. 71QRTCh. 3 - Prob. 72QRTCh. 3 - Prob. 73QRTCh. 3 - Quicklime, CaO, is formed when calcium hydroxide...Ch. 3 - Prob. 75QRTCh. 3 - Disulfur dichloride, which has a revolting smell,...Ch. 3 - Prob. 77QRTCh. 3 - Prob. 78QRTCh. 3 - Quinone, which is used in the dye industry and in...Ch. 3 - l-Dopa is a drug used for the treatment of...Ch. 3 - Write the balanced chemical equation for the...Ch. 3 - Prob. 82QRTCh. 3 - Prob. 83QRTCh. 3 - Prob. 84QRTCh. 3 - Prob. 85QRTCh. 3 - Prob. 86QRTCh. 3 - You need 300. mL of 0.500-M K2Cr2O7. Which method...Ch. 3 - You need to make a 0.300-M solution of NiSO4(aq)....Ch. 3 - You wish to make a 0.200-M solution of CuSO4(aq)....Ch. 3 - Prob. 90QRTCh. 3 - Prob. 91QRTCh. 3 - You mix 25.0 mL of 0.234-M FeCl3 solution with...Ch. 3 - A soft drink contains an unknown mass of citric...Ch. 3 - Prob. 94QRTCh. 3 - Prob. 95QRTCh. 3 - Potassium hydrogen phthalate, KHC8H4O4, is used to...Ch. 3 - Prob. 97QRTCh. 3 - Prob. 98QRTCh. 3 - Prob. 99QRTCh. 3 - Prob. 100QRTCh. 3 - Boron forms an extensive series of compounds with...Ch. 3 - Prob. 102QRTCh. 3 - Prob. 103QRTCh. 3 - Prob. 104QRTCh. 3 - Prob. 105QRTCh. 3 - Azurite is a copper-containing mineral that often...Ch. 3 - Prob. 107QRTCh. 3 - Prob. 108QRTCh. 3 - Vitamin C is ascorbic acid, HC6H7O6, which can be...Ch. 3 - Prob. 110QRTCh. 3 - Prob. 111QRTCh. 3 - Prob. 112QRTCh. 3 - Prob. 113QRTCh. 3 - Prob. 114QRTCh. 3 - Prob. 115QRTCh. 3 - Prob. 116QRTCh. 3 - Prob. 117QRTCh. 3 - Prob. 118QRTCh. 3 - Prob. 119QRTCh. 3 - Prob. 120QRTCh. 3 - Ammonia can be formed by a direct reaction of...Ch. 3 - Carbon monoxide burns readily in oxygen to form...Ch. 3 - Prob. 123QRTCh. 3 - Write a balanced chemical equation that represents...Ch. 3 - A student set up an experiment for six different...Ch. 3 - A weighed sample of a metal is added to liquid...Ch. 3 - Prob. 127QRTCh. 3 - Prob. 128QRTCh. 3 - Each box represents a tiny volume in an aqueous...Ch. 3 - Consider the chemical reaction 2 S + 3 O2 → 2 SO3....Ch. 3 - Prob. 131QRTCh. 3 - Prob. 132QRTCh. 3 - Prob. 133QRTCh. 3 - Prob. 134QRTCh. 3 - Prob. 135QRTCh. 3 - Prob. 136QRTCh. 3 - Prob. 137QRTCh. 3 - Prob. 138QRTCh. 3 - Prob. 139QRTCh. 3 - Prob. 140QRTCh. 3 - Prob. 141QRTCh. 3 - Prob. 142QRTCh. 3 - In a reaction, 1.2 g element A reacts with exactly...Ch. 3 - Prob. 144QRTCh. 3 - When solutions of silver nitrate and sodium...Ch. 3 - Nickel metal reacts with aqueous silver nitrate in...Ch. 3 - Prob. 147QRTCh. 3 - Prob. 148QRTCh. 3 - Prob. 149QRTCh. 3 - Prob. 150QRTCh. 3 - A mountain lake that is 4.0 km × 6.0 km with an...Ch. 3 - Prob. 152QRTCh. 3 - Prob. 153QRTCh. 3 - Prob. 154QRTCh. 3 - Prob. 155QRTCh. 3 - Ethanol, C2H5OH, is a gasoline additive that can...Ch. 3 - Prob. 157QRTCh. 3 - Prob. 3.ACPCh. 3 - Prob. 3.BCPCh. 3 - Prob. 3.DCPCh. 3 - Prob. 3.ECPCh. 3 - Prob. 3.FCPCh. 3 - Prob. 3.GCP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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