Physics (5th Edition)
5th Edition
ISBN: 9780134051802
Author: Walker
Publisher: PEARSON
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Question
Chapter 31, Problem 5CQ
(a)
To determine
The upper limit to the wavelength of lines in the spectrum of hydrogen.
(b)
To determine
The lower limit to the wavelength of lines in the spectrum of hydrogen.
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Compare the Balmer series of hydrogen with the series where n ℓ= 4 for the ionized helium atom He+. What is the difference between the wavelengths of the L ∝ and Lℓ line of hydrogen and the nu = 6 and 8 of He+? Is there a wavelength of the Balmer series that is very similar to any wavelength values where n ℓ = 4 in He+? Explain.
1) The Lyman series of lines in the emission spectrum of hydrogen corresponds to transitions from various excited states to the n1 = 1 orbit. Calculate the wavelength (in nm) of the energy line (n = 11) in the Lyman series to five significant figures. (RH = 109677.57 cm-1). Think about where this is in the spectrum.
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A doubly ionized lithium atom (Li++) is one that has had two of its three electrons removed. The energy levels of the remaining single-electron ion are closely related to those of the hydrogen atom. The nuclear charge for lithium is +3e instead of just +e. How are the energy levels related to those of hydrogen? How is the radius of the ion in the ground level related to that of the hydrogen atom? Explain.
Chapter 31 Solutions
Physics (5th Edition)
Ch. 31.1 - Prob. 1EYUCh. 31.2 - Prob. 2EYUCh. 31.3 - Prob. 3EYUCh. 31.4 - Prob. 4EYUCh. 31.5 - Prob. 5EYUCh. 31.6 - Prob. 6EYUCh. 31.7 - Prob. 7EYUCh. 31 - Prob. 1CQCh. 31 - Prob. 2CQCh. 31 - Prob. 3CQ
Ch. 31 - Prob. 4CQCh. 31 - Prob. 5CQCh. 31 - Prob. 6CQCh. 31 - Prob. 7CQCh. 31 - Prob. 8CQCh. 31 - Prob. 9CQCh. 31 - Prob. 1PCECh. 31 - Prob. 2PCECh. 31 - Prob. 3PCECh. 31 - Prob. 4PCECh. 31 - Prob. 5PCECh. 31 - Prob. 6PCECh. 31 - Prob. 7PCECh. 31 - Prob. 8PCECh. 31 - Prob. 9PCECh. 31 - Prob. 10PCECh. 31 - Prob. 11PCECh. 31 - Prob. 12PCECh. 31 - Prob. 13PCECh. 31 - Prob. 14PCECh. 31 - Prob. 15PCECh. 31 - Prob. 16PCECh. 31 - Prob. 17PCECh. 31 - Prob. 18PCECh. 31 - Prob. 19PCECh. 31 - Prob. 20PCECh. 31 - Prob. 21PCECh. 31 - Prob. 22PCECh. 31 - Prob. 23PCECh. 31 - Prob. 24PCECh. 31 - Prob. 25PCECh. 31 - Prob. 26PCECh. 31 - Prob. 27PCECh. 31 - Prob. 28PCECh. 31 - Prob. 29PCECh. 31 - Prob. 30PCECh. 31 - Prob. 31PCECh. 31 - Prob. 32PCECh. 31 - Prob. 33PCECh. 31 - Prob. 34PCECh. 31 - Prob. 35PCECh. 31 - Prob. 36PCECh. 31 - Prob. 37PCECh. 31 - Prob. 38PCECh. 31 - Prob. 39PCECh. 31 - Prob. 40PCECh. 31 - Prob. 41PCECh. 31 - Prob. 42PCECh. 31 - Prob. 43PCECh. 31 - Prob. 44PCECh. 31 - Prob. 45PCECh. 31 - Prob. 46PCECh. 31 - Prob. 47PCECh. 31 - Prob. 48PCECh. 31 - Prob. 49PCECh. 31 - Prob. 50PCECh. 31 - Prob. 51PCECh. 31 - Prob. 52PCECh. 31 - Give the electronic configuration for the ground...Ch. 31 - Prob. 54PCECh. 31 - Prob. 55PCECh. 31 - Prob. 56PCECh. 31 - The configuration of the outer electrons in Ni is...Ch. 31 - Prob. 58PCECh. 31 - Prob. 59PCECh. 31 - Prob. 60PCECh. 31 - Prob. 61PCECh. 31 - Prob. 62PCECh. 31 - Prob. 63PCECh. 31 - Prob. 64PCECh. 31 - Prob. 65PCECh. 31 - Prob. 66PCECh. 31 - Prob. 67PCECh. 31 - Prob. 68GPCh. 31 - Prob. 69GPCh. 31 - Prob. 70GPCh. 31 - Prob. 71GPCh. 31 - Prob. 72GPCh. 31 - Prob. 73GPCh. 31 - Prob. 74GPCh. 31 - Prob. 75GPCh. 31 - Prob. 76GPCh. 31 - Prob. 77GPCh. 31 - Prob. 78GPCh. 31 - Prob. 79GPCh. 31 - Prob. 80GPCh. 31 - Prob. 81GPCh. 31 - Prob. 82GPCh. 31 - Prob. 83GPCh. 31 - Prob. 84PPCh. 31 - Prob. 85PPCh. 31 - Prob. 86PPCh. 31 - Prob. 87PPCh. 31 - Prob. 88PPCh. 31 - Prob. 89PP
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- (a) If one subshell of an atom has 9 electrons in it, what is the minimum value of l ? (b) What is the spectroscopic notation for this atom, if this subshell is part of the n=3 shell?arrow_forwardIn extreme-temperature environments, such as those existing in a solar corona, atoms may be ionized by undergoing collisions with other atoms. One example of such ionization in the solar corona is the presence of C5+ ions, detected in the Fraunhofer spectrum. (a) By what factor do the energies of the C5+ ion scale compare to the energy spectrum of a hydrogen atom? (b) What is the wavelength of the first line in the Paschen series of C5+ ? (c) In what part of the spectrum are these lines located?arrow_forward(a) What is the minimum value of 1 for a subshell that has 11 electrons in it? (b) If this subshell is in the n=5 shell, what is the spectroscopic notation for this atom?arrow_forward
- A beryllium ion with a single electron (denoted Be3+) is in an excited state with radius the same as that of the ground state of hydrogen. (a) What is n for the Be3+ ion? (b) How much energy in eV is needed to ionize the ion from this excited state?arrow_forward(a) What is the momentum of a 0.0100-nm-wavelength photon that could detect details of an atom? (b) What is its energy in MeV?arrow_forwardThe ion Li2+ makes ail atomic transition from ail n = 4 state to ail n = 2 state, (a) What is the energy of the photon emitted during the transition? (b) What is the wavelength of the photon?arrow_forward
- (a) If one subshell of an atom has nine electrons in it, what is the minimum value of (b) What is the spectroscopic notation for this atom, if this subshell is part of the n = 3 shell?arrow_forward(a) Calculate the velocity of an electron that has a wavelength of 1.00 m. (b) Through what voltage must the electron be accelerated to have this velocity?arrow_forwardA physicist is watching a 15-kg orangutan at a zoo swing lazily in a tire at the end of a rope. He (the physicist) notices that each oscillation takes 3.00 s and hypothesizes that the energy is quantized. (a) What is the difference in energy in joules between allowed oscillator states? (b) What is the value of n for a state where the energy is 5.00 J? (c) Can the quantization be observed?arrow_forward
- Explain why spectral lines of the hydrogen atom are split by an external magnetic field. What determines the number and spacing of these lines?arrow_forward(a) Using the Pauli exclusion principle and the rules relating the allowed values of the quantum numbers (n,l,ml,ms), prove that the maximum number of electrons in a subshell is 2n2. (b) In a similar manner, prove that the maximum number of electrons in a shell is 2n2.arrow_forward(a) List all possible sets of quantum numbers (n,l,ml,ms) for the n=3 shell, and determine the number of electrons that can be in the shell and each of its subshells. (b) Show that the number of electrons in the shell equals 2n2and that the number in each subshell is 2(2l+1).arrow_forward
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