Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 3, Problem 91IL
Interpretation Introduction

Interpretation:

Preparation of MgCl2 other than given way has to be suggested.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Chapter 3 Solutions

Chemistry & Chemical Reactivity

Ch. 3.9 - Prob. 1.1ACPCh. 3.9 - Prob. 1.2ACPCh. 3.9 - Prob. 1.3ACPCh. 3.9 - Prob. 1.4ACPCh. 3.9 - Prob. 1.5ACPCh. 3.9 - Prob. 2.1ACPCh. 3.9 - Prob. 2.2ACPCh. 3.9 - Prob. 3.1ACPCh. 3.9 - Prob. 3.2ACPCh. 3 - The equation for the oxidation of phosphorus in...Ch. 3 - Write an equation from the following description:...Ch. 3 - The equation for the reaction of phosphorus and...Ch. 3 - The equation for the reaction of aluminum and...Ch. 3 - Oxidation of 1.00 g of carbon monoxide, CO,...Ch. 3 - A 0.20 mol sample of magnesium burns in air to...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 9PSCh. 3 - Prob. 10PSCh. 3 - Prob. 11PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Prob. 13PSCh. 3 - Prob. 14PSCh. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 16PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 28PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 31PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 33PSCh. 3 - Prob. 34PSCh. 3 - Prob. 35PSCh. 3 - Prob. 36PSCh. 3 - Prob. 37PSCh. 3 - Prob. 38PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 41PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 45PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 51PSCh. 3 - Prob. 52PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 55PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 60PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 62PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 65PSCh. 3 - Prob. 66PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 69GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 71GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 79GQCh. 3 - Prob. 80GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 82GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 85GQCh. 3 - Prob. 86GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 89ILCh. 3 - Prob. 90ILCh. 3 - Prob. 91ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 97SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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