Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 72GQ
Name two anions that combine with Al3+ ion to produce water-soluble compounds.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
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Chapter 3 Solutions
Chemistry & Chemical Reactivity
Ch. 3.2 - (a) Butane gas, C4H10, can burn completely in air...Ch. 3.4 - Predict whether each of the following ionic...Ch. 3.5 - In each of the following cases, does a...Ch. 3.5 - In each of the following cases, aqueous solutions...Ch. 3.6 - Prob. 3.5CYUCh. 3.6 - Prob. 3.6CYUCh. 3.7 - Prob. 3.7CYUCh. 3.8 - Assign an oxidation number to the underlined atom...Ch. 3.8 - Prob. 3.9CYUCh. 3.9 - Prob. 3.10CYU
Ch. 3.9 - Prob. 1.1ACPCh. 3.9 - Prob. 1.2ACPCh. 3.9 - Prob. 1.3ACPCh. 3.9 - Prob. 1.4ACPCh. 3.9 - Prob. 1.5ACPCh. 3.9 - Prob. 2.1ACPCh. 3.9 - Prob. 2.2ACPCh. 3.9 - Prob. 3.1ACPCh. 3.9 - Prob. 3.2ACPCh. 3 - The equation for the oxidation of phosphorus in...Ch. 3 - Write an equation from the following description:...Ch. 3 - The equation for the reaction of phosphorus and...Ch. 3 - The equation for the reaction of aluminum and...Ch. 3 - Oxidation of 1.00 g of carbon monoxide, CO,...Ch. 3 - A 0.20 mol sample of magnesium burns in air to...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 9PSCh. 3 - Prob. 10PSCh. 3 - Prob. 11PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Prob. 13PSCh. 3 - Prob. 14PSCh. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 16PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 28PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 31PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 33PSCh. 3 - Prob. 34PSCh. 3 - Prob. 35PSCh. 3 - Prob. 36PSCh. 3 - Prob. 37PSCh. 3 - Prob. 38PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 41PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 45PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 51PSCh. 3 - Prob. 52PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 55PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 60PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 62PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 65PSCh. 3 - Prob. 66PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 69GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 71GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 79GQCh. 3 - Prob. 80GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 82GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 85GQCh. 3 - Prob. 86GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 89ILCh. 3 - Prob. 90ILCh. 3 - Prob. 91ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 97SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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