Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 3, Problem 86SCQ
There are many ionic compounds that dissolve in water to a very small extent. One example is lead(II) chloride. When it dissolves an equilibrium is established between the solid salt and its component ions. Suppose you stir some solid PbCl2 into water. Explain how you would prove that the compound dissolves but to a small extent? Is the dissolving process product-favored or reactant-favored?
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Chapter 3 Solutions
Chemistry & Chemical Reactivity
Ch. 3.1 - The reaction of aluminum with bromine is shown...Ch. 3.1 - If you were to use 8000 atoms of Al, how many...Ch. 3.2 - (a) Butane gas, C4H10, can burn completely in air...Ch. 3.2 - The (unbalanced) equation describing the oxidation...Ch. 3.3 - Prob. 1RCCh. 3.4 - Predict whether each of the following ionic...Ch. 3.4 - Prob. 1RCCh. 3.4 - Prob. 2RCCh. 3.4 - Prob. 3RCCh. 3.5 - In each of the following cases, does a...
Ch. 3.5 - In each of the following cases, aqueous solutions...Ch. 3.5 - Prob. 1RCCh. 3.5 - What is the net ionic equation for the reaction of...Ch. 3.6 - Prob. 1CYUCh. 3.6 - Prob. 2CYUCh. 3.6 - Prob. 1RCCh. 3.6 - 2. The hydrogen phosphate ion is amphiprotic....Ch. 3.6 - What is the net ionic equation for the reaction of...Ch. 3.6 - Prob. 4RCCh. 3.7 - Prob. 1CYUCh. 3.7 - Prob. 1RCCh. 3.8 - Assign an oxidation number to the underlined atom...Ch. 3.8 - Prob. 2CYUCh. 3.8 - 1. What is the oxidation number of Mn in...Ch. 3.8 - Prob. 2RCCh. 3.8 - 3. In which of the manganese compounds below does...Ch. 3.9 - Prob. 1CYUCh. 3.9 - 1. Sometimes a reaction can fall in more than one...Ch. 3.9 - Prob. 1QCh. 3.9 - Prob. 2QCh. 3.9 - Prob. 3QCh. 3.9 - Prob. 4QCh. 3.9 - Prob. 5QCh. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 3PSCh. 3 - Prob. 4PSCh. 3 - Prob. 5PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 8PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 20PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 23PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 25PSCh. 3 - Prob. 26PSCh. 3 - Prob. 27PSCh. 3 - Prob. 28PSCh. 3 - Prob. 29PSCh. 3 - Prob. 30PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 33PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 37PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 43PSCh. 3 - Prob. 44PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 47PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 52PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 54PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 57PSCh. 3 - Prob. 58PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 61GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 63GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 71GQCh. 3 - Prob. 72GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 74GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 77GQCh. 3 - Prob. 78GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 81ILCh. 3 - Prob. 82ILCh. 3 - Prob. 83ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 89SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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- Write the equilibrium constant expression for each of the following reactions in terms of concentrations. (a) CO2(g) + C(s) 2 CO(g) (b) [Cu(NH3)4)2+(aq) Cu2+(aq) + 4 NH3(aq) (c) CH3CO2H(aq) + H2O() CH3CO2(aq) + H3O+(aq)arrow_forwardWhat is the law of mass action? Is it true that the value of K depends on the amounts of reactants and products mixed together initially? Explain. Is it true that reactions with large equilibrium constant values are very fast? Explain. There is only one value of the equilibrium constant for a particular system at a particular temperature, but there is an infinite number of equilibrium positions. Explain.arrow_forwardBecause barium sulfate is opaque to X-rays, it is suspended in water and taken internally to make the gastrointestinal tract visible in an X-ray photograph. Although barium ion is quite toxic, barium sulfate’s /Csp of 1.1 X 10-,<) gives it such low solubility' that it can be safely consumed. What is the molar solubility' of BaSO4. What is its solubility' in grams per 100 g of water?arrow_forward
- Sodium chloride is added to water (at 25C) until it is saturated. Calculate the Cl concentration in such a solution. Species G(kJ/mol) NaCl(s) 384 Na+(aq) 262 Cl(aq) 131arrow_forwardThe following question is taken from a Chemistry Advanced Placement Examination and is used with the permission of the Educational Testing Service. Solve the following problem: MgF2(s)Mg2+(aq)+2F(aq) In a saturated solution of MgF2 at 18 C, the concentration of Mg2+ is 1.21103M . The equilibrium is represented by the preceding equation. (a) Write the expression for the solubility-product constant, Ksp, and calculate its value at 18 C. (b) Calculate the equilibrium concentration of Mg2+ in 1.000 L of saturated MgF2 solution at 18 C to which 0.100 mol of solid KF has been added. The KF dissolves completely. Assume the volume change is negligible. (c) Predict whether a precipitate of MgF2 will form when 100.0 mL of a 3.00103 -M solution of Mg(NO3)2 is mixed with 200.0 mL of a .2.00103 -M solution of NaF at 18 C. Show the calculations to support your prediction.. (d) At 27 C the concentration of Mg2+ in a saturated solution of MgF2 is 1.17103M . Is the dissolving of MgF2 in water all endothermic or an exothermic process? Give an explanation to support your conclusion.arrow_forwardBecause calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?arrow_forward
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