Equal amounts of two acids—HCl and HCO2H (formic acid)—are placed in aqueous solution. When equilibrium has been achieved, the HCl solution has a much greater electrical conductivity than the HCO2H solution. Which reaction is more product-favored at equilibrium?
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Chapter 3 Solutions
Chemistry & Chemical Reactivity
- Complete each of these reactions by filling in the blanks. Predict whether each reaction is product-favored or reactant-favored, and explain your reasoning. (a) _________ (aq) + Br(aq) NH3(aq) + HBr(aq) (b) CH3COOH(aq) + CN(aq) ________ (aq) + HCN(aq) (c) ________ (aq)+H2O () NH3(aq) + OH(aq)arrow_forwardMost naturally occurring acids are weak acids. Lactic acid is one example. CH3CH(OH)CO2H(s)+H2O(l)H3O+(aq)+CH3CH(OH)CO2(aq) If you place some lactic acid in water, it will ionize to a small extent, and an equilibrium will be established. Suggest some experiments to prow that this is a weak acid and that the establishment of equilibrium is a reversible process.arrow_forwardDescribe any thermochemical (heat of reaction) evidence for the Arrhenius concept.arrow_forward
- Hi, I only need help with question # 3. Equilibrium Write the equilibrium expressions for the following reactions:a) 3Fe(s) + 4H2O(g) ↔ Fe3O4(s) + 4H2(g)b) CH3COOH(aq) + H2O(l) ↔ CH3COO-(aq) + H3O+(aq)c) N2(g) + 3Br2(g) ↔ 2NBr3(s)d) CaCl2(s) ↔ Ca2+(aq) + 2Cl-(aq) Consider the following equilibrium: CH3COOH(l) + C2H5OH(l) ↔ CH3CO2C2H5(l) + H2O(l) Keq =2.2 What must the concentration of water be for a mixture with [CH3COOH]= 0.10M, [CH3CO2C2H5]=2.0M, [C2H5OH]= 5.0M to be at equilibrium? Note: water is NOT the solvent in this reaction, therefore it will be included in the equilibrium expression. 3. Predict the direction of the following equilibrium shifts (Please label Forward (F) or Reverse (R)): a) H2O (g) + CO(g)↔ H2(g) + CO2(g) Water is removed? ___Hydrogen is added? ___Carbon monoxide is added? ___b) 4Fe(s) + 3O2(g) ↔ 2Fe2O3(s) + 1648 kJThe temperature is increased? ___The pressure is increased? ___c) CaCl2(aq) ↔ Ca2+(aq) + 2Cl-(aq) NaCl is added? ___AgNO3 is added? ___arrow_forwardFor the following equilibrium reaction: NaOH(Aq) + HCl(aq) HOH(aq) + NaCl(aq) + Δ What happens if you add: A) KCl B)KBrarrow_forwardAqueous Ammonia Solution (with phenolphthalein) NH3 (aq) + H2O (l) = NH4+1 (aq) + OH-1 (aq) What happens to equilibrium by adding HCl to the solution? The reactants are colorless and products are pink.arrow_forward
- Methanoic acid is also called formic acid. It has the chemical formula HCOOH(l). It is a colourless fuming liquid that is mainly used as a preservative. It exhibits the following equilibrium in water:HCOOH(aq) + H2O(l) → HCOO–(aq) + H3O+(aq) 4) The concentration of the hydroxide ion, OH-(aq), in an aqueous solution is 2.5 x 10–3 mol/L. What is the pH of the solution? PLEASE HELP THIS IS VERY URGENTarrow_forwardSwimming pool disinfectants produce hypochlorous acid upon dissolution. The weak acid ionizes as follows: HClO (aq) ⇄ H+ (aq) + ClO‒ (aq) Ka=3.0 x 10 ‒8 As strong oxidizing agents, both acid and its conjugate base kill bacteria. However, too high [HClO] is irritating to swimmers’ eyes and too high [ClO‒] will cause the ions to decompose in sunlight. The recommended pH to circumvent both problems is 7.8. Determine the ratio of the weak acid and its conjugate base at this pH.arrow_forwardWrite the equilibrium constant expression for this reaction: 2 H* (aq) + C₂0 (aq) H₂C₂O4(aq) X Sarrow_forward
- Write the equilibrium constant expression, K, for the following reaction. Please enter the compounds in the order given in the reaction. If either the numerator or denominator is blank, please enter 1 CH3 COOH (аq) + H20(1) : H30+(aq) + CH3 COO¯ (aq) K =arrow_forward1arrow_forwardUse Le Chatelier’s principle to determine whether the equilibrium for the endothermic reaction below shifts to the left, right, or does not change under each condition listed: 4Fe(s) + 3O2(g) → 2Fe2O3(aq) The pressure is increased The temperature is raised Some iron is added Some oxygen is removedarrow_forward
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