Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 42PS
The mineral rhodothrosite is manganese(Ⅱ) carbonate. Write an overall, balanced equation for the reaction of the mineral with hydrochloric acid, and name the products.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 3 Solutions
Chemistry & Chemical Reactivity
Ch. 3.1 - The reaction of aluminum with bromine is shown...Ch. 3.1 - If you were to use 8000 atoms of Al, how many...Ch. 3.2 - (a) Butane gas, C4H10, can burn completely in air...Ch. 3.2 - The (unbalanced) equation describing the oxidation...Ch. 3.3 - Prob. 1RCCh. 3.4 - Predict whether each of the following ionic...Ch. 3.4 - Prob. 1RCCh. 3.4 - Prob. 2RCCh. 3.4 - Prob. 3RCCh. 3.5 - In each of the following cases, does a...
Ch. 3.5 - In each of the following cases, aqueous solutions...Ch. 3.5 - Prob. 1RCCh. 3.5 - What is the net ionic equation for the reaction of...Ch. 3.6 - Prob. 1CYUCh. 3.6 - Prob. 2CYUCh. 3.6 - Prob. 1RCCh. 3.6 - 2. The hydrogen phosphate ion is amphiprotic....Ch. 3.6 - What is the net ionic equation for the reaction of...Ch. 3.6 - Prob. 4RCCh. 3.7 - Prob. 1CYUCh. 3.7 - Prob. 1RCCh. 3.8 - Assign an oxidation number to the underlined atom...Ch. 3.8 - Prob. 2CYUCh. 3.8 - 1. What is the oxidation number of Mn in...Ch. 3.8 - Prob. 2RCCh. 3.8 - 3. In which of the manganese compounds below does...Ch. 3.9 - Prob. 1CYUCh. 3.9 - 1. Sometimes a reaction can fall in more than one...Ch. 3.9 - Prob. 1QCh. 3.9 - Prob. 2QCh. 3.9 - Prob. 3QCh. 3.9 - Prob. 4QCh. 3.9 - Prob. 5QCh. 3 - Write balanced chemical equations for the...Ch. 3 - Write balanced chemical equations for the...Ch. 3 - Prob. 3PSCh. 3 - Prob. 4PSCh. 3 - Prob. 5PSCh. 3 - Balance the following equations, and name each...Ch. 3 - Equal amounts of two acidsHCl and HCO2H (formic...Ch. 3 - Prob. 8PSCh. 3 - What is an electrolyte? How can you differentiate...Ch. 3 - Name and give the formulas of two acids that are...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - Which compound or compounds in each of the...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - The following compounds are water-soluble. What...Ch. 3 - Decide whether each of the following is...Ch. 3 - Decide whether each of the following is...Ch. 3 - Balance the equation for the following...Ch. 3 - Balance the equation for the following...Ch. 3 - Predict the products of each precipitation...Ch. 3 - Prob. 20PSCh. 3 - Write a balanced equation for the ionization of...Ch. 3 - Write a balanced equation for the ionization of...Ch. 3 - Prob. 23PSCh. 3 - Phosphoric add can supply one, two, or three H3O+...Ch. 3 - Prob. 25PSCh. 3 - Prob. 26PSCh. 3 - Prob. 27PSCh. 3 - Prob. 28PSCh. 3 - Prob. 29PSCh. 3 - Prob. 30PSCh. 3 - Write an equation that describes the equilibrium...Ch. 3 - Write an equation that describes the equilibrium...Ch. 3 - Prob. 33PSCh. 3 - Write two chemical equations, one in which H2PO4...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Balance the following equations, and then write...Ch. 3 - Prob. 37PSCh. 3 - Balance each of the following equations, and then...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Write balanced net ionic equations for the...Ch. 3 - Siderite is a mineral consisting largely of...Ch. 3 - The mineral rhodothrosite is manganese()...Ch. 3 - Prob. 43PSCh. 3 - Prob. 44PSCh. 3 - Determine the oxidation number of each element in...Ch. 3 - Determine the oxidation number of each element in...Ch. 3 - Prob. 47PSCh. 3 - Which two of the following reactions are...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - In the following reactions, decide which reactant...Ch. 3 - Balance the following equations, and then classify...Ch. 3 - Prob. 52PSCh. 3 - Classify each of the following reactions as a...Ch. 3 - Prob. 54PSCh. 3 - Balance each of the following equations, and...Ch. 3 - Complete and balance the equations below, and...Ch. 3 - Prob. 57PSCh. 3 - Prob. 58PSCh. 3 - Balance the following equations: (a) for the...Ch. 3 - Balance the following equations: (a) for the...Ch. 3 - Prob. 61GQCh. 3 - Give the formula for each of the following...Ch. 3 - Prob. 63GQCh. 3 - Name two anions that combine with Al3+ ion to...Ch. 3 - Write the net ionic equation and identify the...Ch. 3 - Identify and name the water-insoluble product in...Ch. 3 - Bromine is obtained from sea water by the...Ch. 3 - Identify each of the blowing substances as a...Ch. 3 - The mineral dolomite contains magnesium...Ch. 3 - Aqueous solutions of ammonium sulfide, (NH4)2S,...Ch. 3 - Prob. 71GQCh. 3 - Prob. 72GQCh. 3 - Balance equations for these reactions that occur...Ch. 3 - Prob. 74GQCh. 3 - You are given mixtures containing the following...Ch. 3 - Identify, from each list below, the compound or...Ch. 3 - Prob. 77GQCh. 3 - Prob. 78GQCh. 3 - Gas evolution was observed when a solution of Na2S...Ch. 3 - Prob. 81ILCh. 3 - Prob. 82ILCh. 3 - Prob. 83ILCh. 3 - A Suggest a laboratory method for preparing barium...Ch. 3 - The Toliens test for the presence of reducing...Ch. 3 - There are many ionic compounds that dissolve in...Ch. 3 - Most naturally occurring acids are weak acids....Ch. 3 - You want to prepare barium chloride, BaC12, using...Ch. 3 - Prob. 89SCQCh. 3 - A Describe how to prepare zinc chloride by (a) an...Ch. 3 - A common method for analyzing for the nickel...Ch. 3 - The presence of arsenic in a sample that may also...
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