Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 3, Problem 3.54P
Interpretation Introduction

(a)

Interpretation: The functional groups present in the given compound are to be predicted.

Concept introduction: In ball-and-stick model, each colored ball represents a specific atom and each stick represents a bond. In this model, each black ball represents C atoms, each gray ball represents H atoms, each blue ball represents N atoms, and each red ball represents O atoms.

Interpretation Introduction

(b)

Interpretation: The most acidic proton is to be predicted.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

Interpretation Introduction

(c)

Interpretation: The most basic proton is to be predicted.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

Interpretation Introduction

(d)

Interpretation: The intermolecular forces which are present between two molecules of fentanyl is to be predicted.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

Interpretation Introduction

(e)

Interpretation: The isomer which has a higher boiling point is to be drawn.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

Interpretation Introduction

(f)

Interpretation: The sites which can hydrogen bond to water are to be predicted.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

Interpretation Introduction

(g)

Interpretation: The electrophilic carbons in the given compound are to be labeled.

Concept introduction: Functional groups containing a C=O bond are aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides. The polar C=O bond makes the carbonyl carbon electrophilic, while lone pairs on carbonyl oxygen make it a nucleophile and permit to react as a base and nucleophile.

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A complete tensile test was performed on a magnesium specimen of 12 mm diameter and 30 mm length, until breaking. The specimen is assumed to maintain a constant volume. Calculate the approximate value of the actual stress at breaking. TABLE. The tensile force F and the length of the specimen are represented for each L until breaking. F/N L/mm 0 30,0000 30,0296 5000 10000 30,0592 15000 30,0888 20000 30,15 25000 30,51 26500 30,90 27000 31,50 26500 32,10 25000 32,79
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Chapter 3 Solutions

Organic Chemistry

Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Nonactin and valinomycin each contain only two...Ch. 3 - Prob. 3.17PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - The fact that sweet-tasting carbohydrates like...Ch. 3 - 3.29 Identify the functional groups in the...Ch. 3 - Prob. 3.22PCh. 3 - 3.32 Identify the functional groups in each...Ch. 3 - Draw the seven constitutional isomers having...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - Prob. 3.32PCh. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Explain the observed trend in the melting points...Ch. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.41PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - THC is the active component in marijuana, and...Ch. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Label the electrophilic and nucleophilic sites in...Ch. 3 - By using only electron density arguments,...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Recall from section 1.10B that there is restricted...
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