Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 3, Problem 3.25P
Identify each
represents a lactone-a cyclic ester- and which represents a lactam-a cyclic amide?
a. 
b. 
c. 
d. 
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17. Which functional groups are in the following molecule of aspirin?
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b. a benzene ring, two ketones, an ether, and an alcohol
a benzene ring, a carboxylic acid, an ether, and a ketone
d. a benzene ring, a carboxylic acid, and an ester
a.
c.
The hydrolysis of an amide in acidic conditions forms
A. a carboxylate salt and an alcohol
B. a carboxylate salt and an amine
C. an alcohol and an amine salt (an ammonium ion)
D. a carboxylic acid and an amine salt (an ammonium ion)
Jj.166.
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Chapter 3 Solutions
Organic Chemistry
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Draw the structure of a compound fitting each...Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Prob. 3.6PCh. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Nonactin and valinomycin each contain only two...Ch. 3 - Prob. 3.17PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - The fact that sweet-tasting carbohydrates like...Ch. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.22PCh. 3 - 3.32 Identify the functional groups in each...Ch. 3 - Draw the seven constitutional isomers having...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - Prob. 3.32PCh. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Explain the observed trend in the melting points...Ch. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.41PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - THC is the active component in marijuana, and...Ch. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Label the electrophilic and nucleophilic sites in...Ch. 3 - By using only electron density arguments,...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Recall from section 1.10B that there is restricted...
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- What are the functional groups present in this antibacterial antibiotic? A. Amide, thioether, aldehyde, phenol, carboxylic acid B. Amide, thioether, ketone, amine, phenol, carboxylic acid C. Amide, thioether, ketone, phenol, carboxylic acid D. Thioether, ketone, amine, phenol, carboxylic acid A brief explanation would be highly appreciated + upvotearrow_forwardWhich compound is more likely to be a general anesthetic? Explain your choice.arrow_forwardName each compound depicted in the ball-and-stick models.arrow_forward
- What amine is formed by reduction of each amide?arrow_forwardDraw a structural formula for each amine and amine derivative. Q.) trans-2-Aminocyclohexanolarrow_forward1. Which statement best described the ability of amines to hydrogen bond? A. Primary, secondary and tertiary amines can all hydrogen bond with molecules identical to themselves. B. Primary and secondary amines can hydrogen bond with molecules identical to themselves, but tertiary amines cannot. C. Only primary amines can hydrogen bond with molecules identical to themselves. Secondary and tertiary amines cannot. D. Primary, secondary and tertiary amines cannot hydrogen bond with molecules identical to themselves, but the can hydrogen bond with water.arrow_forward
- amine, (2) an amide, or (3) both an amine and an amide. 17-106 Classify each of the following compounds as (1) an amine, (2) an amide, or (3) both an amine and an NH2 b. `NH a. H2N H d. с.arrow_forwardErythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OHarrow_forwardDraw a structural formula for each amine and amine derivative. Q.) Benzylaminearrow_forward
- Identify the functional groups in the two molecules shown below. Then, for each ester or amide functional group, write a reaction showing how the molecule could be made. H. H.arrow_forwardWhat are the functional groups present in this antibacterial antibiotic? A. Nitro, phenyl, amine, carbonyl, hydroxyl B. Nitro, phenyl, amine, carbonyl, C. Nitro, phenyl, amine, hydroxyl D. Nitro, phenol, amine, carbonyl, hydroxyl A brief explanation would be highly appreciated + upvotearrow_forwardDraw a structural formula for each amine and amine derivative. Q.)1-Phenyl-2-propanamine (amphetamine)arrow_forward
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