(a) Interpretation: Whether two unique configurations about double bond are possible in the given compound is to be explained. Concept introduction: For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Question

Want to see the full answer?

Answer 1

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

For a given molecular formula of a hydrocarbon, such as C6H14, draw the structural formulae of its different structural isomers. For a given structural isomer, be able to draw several diagrams that all represent the same isomer that has been transformed by (a) rotation of the whole molecule and/or (b) rotation around single covalent bonds

For which of the following molecules are there two unique configurations about the double bond? Explain. (a) (CH3)2C=CHCI; (b) H2C=CHCH,CH3; (c) CIHC=CHBr; (d) HC=CCH=CHCI

The average bond energy (enthalpy) for a C=CC=C double bond is 614 kJ/molkJ/mol and that of a C−CC−C single bond is 348 kJ/molkJ/mol. Estimate the energy needed to break only the ππ bond of the double bond of 2-butene. Express your answer numerically in joules per molecule.

Answer 2

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 6

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 7

Chapter 3, Problem 3.46P

Interpretation Introduction

(a)

Interpretation:

Whether two unique configurations about double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether two unique configurations about the double bond are possible in the given compound is to be explained.

Concept introduction:

For a given double bond, cis and trans configurations are possible if the exchange of two groups on one of the doubly bonded atoms results in a different molecule. If one of the carbon atoms of the double bond has two identical atoms or groups attached, then that double bond will not have two distinct configurations. Two groups are cis to each other if they are on the same side of a double bond, and they are trans to each other if they are on opposite sides.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that two unique configurations about the double bond are not possible in the given structure.

Concept explainers

Want to see the full answer?

Chapter 3 Solutions