Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 3, Problem 3.11YT
Interpretation Introduction

Interpretation:

A molecular modeling kit is to be constructed for the given two molecules, and it is to be tried to line one up with the other. Further, it is to be explained whether the two given molecules are the same or different.

Concept introduction:

A double bond will not have two distinct configurations if one carbon of the double bond possesses two identical atoms or groups. Therefore, for cis-trans configuration, the molecule must possess two different groups or atoms on the same carbon of the double bond.

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Draw the structure of ,-diethyl--propylthiopentane.  With explanation
A. Provide a stepwise mechanism for the formation of nerolidyl pyrophosphate fromfarnesylpyrophosphate B. Provide a stepwise mechanism for the formation of carbocation 1 from nerolidylpyrophosphate. Number the backbone carbons of nerolidyl pyrophosphate from 1 to 11 as shown, andinclude the carbon numbering in your structure of 1 C. Following from B, give an arrow-pushing mechanism to convert 1 to 2 and 2 to 3. Use thebackbone carbon numbering from 1 to indicate where carbon atoms ended up in 2 and 3 D. In addition to forming epi-cedrol, carbocation 3 gives three minor byproducts: a diastereomericalcohol and two alkenes. Draw mechanisms that could give rise to these three products
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