(a) Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1 → 6 - α -glycosidic linkage is to be drawn. Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

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2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O₂ / HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI хот Br Solvent Reagent(s) Solvent Reagent(s)

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

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Answer 5

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Answer 6

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 7

Chapter 28, Problem 28.75P

Interpretation Introduction

(a)

Interpretation: The structure of polysaccharide formed by joining D-glucosamine in 1→6-α-glycosidic linkage is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure of disaccharide formed by joining D-mannose and D-glucose in 1→4-β-glycosidic linkage using mannose’s anomeric carbon is to be drawn.

Concept introduction: Monosaccharides are the small units of simple sugars. Disaccharides are formed by two units of monosaccharides. Polysaccharides are made up of small units of monosaccharides. These small units are joined together by glycoside linkage.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure of an Α-N-glycoside formed from D-arabinose and C6H5CH2NH2 is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Answer 12

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Answer 13

Interpretation Introduction

(d)

Interpretation: The structure of ribonucleoside formed from D-ribose and thymine is to be drawn.

Concept introduction: Monosaccharide is the simplest form of carbohydrate. It possesses either ketone or aldehyde with one or more than one hydroxyl (OH) groups. Disaccharides, trisaccharides, oligosaccharides, and polysaccharides all involve monosaccharide as subunits.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 28 - Prob. 28.1P Ch. 28 - Prob. 28.2P Ch. 28 - Label each stereogenic center as R or S. a. b. c....Ch. 28 - Convert the ball-and-stick model to a Fischer...Ch. 28 - Prob. 28.5P Ch. 28 - Prob. 28.6P Ch. 28 - Prob. 28.7P Ch. 28 - Prob. 28.8P Ch. 28 - Prob. 28.9P Ch. 28 - Prob. 28.10P

Solution Summary: The author explains the structure of polysaccharide formed by joining D-glucosamine in 1to 6 -

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