Organic Chemistry-Package(Custom)
Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Chapter 28, Problem 28.1P
Interpretation Introduction

(a)

Interpretation: The structure of ketotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Expert Solution
Check Mark

Answer to Problem 28.1P

The structure of ketotetrose is,

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  1

Figure 1

Explanation of Solution

The name ketotetrose suggests that it is a monosaccharide that contains four carbon atoms and a ketone group. The ketone carbonyl group is present on second carbon atom in ketoses. The structure of ketotetrose is shown in Figure 1.

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  2

Figure 1

Conclusion

The structure of ketotetrose is shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure of aldopentose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Expert Solution
Check Mark

Answer to Problem 28.1P

The structure of aldopentose is,

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  3

Figure 2

Explanation of Solution

The name aldopentose suggests that it is a monosaccharide that contains five carbon atoms and an aldehyde group. The aldehyde carbonyl group is present on first carbon atom in aldoses. The structure of aldopentose is shown in Figure 2.

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  4

Figure 2

Conclusion

The structure of aldopentose is shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure of aldotetrose is to be drawn.

Concept introduction: A monosaccharide in which aldehyde carbonyl group is present at C1 is called aldose whereas a monosaccharide in which ketone carbonyl group is present at C2 is called ketose.

Expert Solution
Check Mark

Answer to Problem 28.1P

The structure of aldotetrose is,

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  5

Figure 3

Explanation of Solution

The name aldotetrose suggests that it is a monosaccharide that contains four carbon atoms and an aldehyde group. The aldehyde carbonyl group is present on first carbon atom in aldoses. The structure of aldotetrose is shown in Figure 3.

Organic Chemistry-Package(Custom), Chapter 28, Problem 28.1P , additional homework tip  6

Figure 3

Conclusion

The structure of aldotetrose is shown in Figure 3.

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Draw the structure of (a) a ketotetrose; (b) an aldopentose; (c) an aldotetrose.
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A) Define "reducing sugar." (b) Sucrose is a disaccharide composed of glucose and fructose (Glc(1 → 2)Fru). Explain why sucrose is not a reducing sugar, even though both glucose and fructose are.

Chapter 28 Solutions

Organic Chemistry-Package(Custom)

Ch. 28 - Prob. 28.11PCh. 28 - Prob. 28.12PCh. 28 - Prob. 28.13PCh. 28 - Prob. 28.14PCh. 28 - Prob. 28.15PCh. 28 - Prob. 28.16PCh. 28 - Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.18PCh. 28 - Prob. 28.19PCh. 28 - Prob. 28.20PCh. 28 - Prob. 28.21PCh. 28 - Draw the products formed when D-arabinose is...Ch. 28 - Prob. 28.23PCh. 28 - Prob. 28.24PCh. 28 - Prob. 28.25PCh. 28 - Prob. 28.26PCh. 28 - Prob. 28.27PCh. 28 - Prob. 28.28PCh. 28 - Prob. 28.29PCh. 28 - Prob. 28.30PCh. 28 - Prob. 28.31PCh. 28 - Prob. 28.32PCh. 28 - Prob. 28.33PCh. 28 - Prob. 28.34PCh. 28 - Problem-28.35 Draw the structures of the...Ch. 28 - Prob. 28.36PCh. 28 - 28.37 Convert each ball-and-stick model to a...Ch. 28 - Prob. 28.38PCh. 28 - Prob. 28.39PCh. 28 - Convert each compound to a Fischer projection and...Ch. 28 - Prob. 28.41PCh. 28 - Prob. 28.42PCh. 28 - Prob. 28.43PCh. 28 - Prob. 28.44PCh. 28 - Prob. 28.45PCh. 28 - Draw both pyranose anomers of each aldohexose...Ch. 28 - Prob. 28.47PCh. 28 - Prob. 28.48PCh. 28 - Prob. 28.49PCh. 28 - Prob. 28.50PCh. 28 - Prob. 28.51PCh. 28 - Prob. 28.52PCh. 28 - Prob. 28.53PCh. 28 - What products are formed when each compound is...Ch. 28 - Prob. 28.55PCh. 28 - Prob. 28.56PCh. 28 - Prob. 28.57PCh. 28 - Prob. 28.58PCh. 28 - 28.58 Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.60PCh. 28 - Prob. 28.61PCh. 28 - Prob. 28.62PCh. 28 - Prob. 28.63PCh. 28 - Prob. 28.64PCh. 28 - Prob. 28.65PCh. 28 - Prob. 28.66PCh. 28 - Prob. 28.67PCh. 28 - Prob. 28.68PCh. 28 - Prob. 28.69PCh. 28 - Prob. 28.70PCh. 28 - Prob. 28.71PCh. 28 - Prob. 28.72PCh. 28 - Prob. 28.73PCh. 28 - Prob. 28.74PCh. 28 - Prob. 28.75PCh. 28 - Prob. 28.76PCh. 28 - Prob. 28.77PCh. 28 - Draw a stepwise mechanism for the following...Ch. 28 - Prob. 28.79P
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