Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 28, Problem 28.13P
Interpretation Introduction
Interpretation:
The structural formula of Cyclic-AMP has to be drawn.
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Cyclic-AMP, first isolated in 1959, is involved in many diverse biological processes as a regulator of metabolic and physiological activity. In it, a single phosphate group is esterified with both the 3' and 5' hydroxyls of adenosine. Draw a structural formula of cyclic-AMP.
(a) Write the deprotonation equations for citric
acid
FÓRMULA
pKal
pK2
pK23
pKa4
он
HO-C–CH2–C–CH2–Ĉ–OH
2.94
4.14
5.82
16.0
0=C–OH
The oxidative decarboxylation of 2-ketobutanoic acid (2-ketobutyric acid) is one step in the breakdown of homocysteine.
Predict the thioester product of the oxidative decarboxylation of 2-ketobutanoic acid, using coenzyme A as the thiol.
Modify this molecule so that it represents the product. Add or remove
atoms or bonds as needed. Use the symbol CoA to represent coenzyme A.
Select
Draw
Rings
Groups
More
Erase
H
H3C-CH2-Ĉ
OH
II
H,C -
C - OH
Chapter 28 Solutions
Organic Chemistry
Ch. 28.1 - Prob. 28.1PCh. 28.2 - Prob. 28.2PCh. 28.2 - Prob. 28.3PCh. 28.3 - Here is a portion of the nucleotide sequence in...Ch. 28.4 - The following section of DNA codes for oxytocin, a...Ch. 28.5 - Prob. 28.6PCh. 28 - Prob. 28.7PCh. 28 - Following are structural formulas for cytosine and...Ch. 28 - Prob. 28.9PCh. 28 - Prob. 28.10P
Ch. 28 - Prob. 28.11PCh. 28 - Prob. 28.12PCh. 28 - Prob. 28.13PCh. 28 - Prob. 28.14PCh. 28 - Prob. 28.15PCh. 28 - Draw a structural formula of the DNA...Ch. 28 - List the postulates of the Watson-Crick model of...Ch. 28 - Prob. 28.18PCh. 28 - Prob. 28.19PCh. 28 - Prob. 28.20PCh. 28 - Prob. 28.21PCh. 28 - Prob. 28.22PCh. 28 - Prob. 28.23PCh. 28 - Prob. 28.24PCh. 28 - Write the DNA complement for 5-ACCGTTAAT-3. Be...Ch. 28 - Prob. 28.26PCh. 28 - Prob. 28.27PCh. 28 - Compare DNA and RNA is these ways. (a)...Ch. 28 - What type of RNA has the shortest lifetime in...Ch. 28 - Prob. 28.30PCh. 28 - Prob. 28.31PCh. 28 - Prob. 28.32PCh. 28 - Write the mRNA codons for the following. (a)...Ch. 28 - Prob. 28.34PCh. 28 - Prob. 28.35PCh. 28 - Prob. 28.36PCh. 28 - Prob. 28.37PCh. 28 - Prob. 28.38PCh. 28 - Prob. 28.39PCh. 28 - What polypeptide is coded for by this mRNA...Ch. 28 - The alpha chain of human hemoglobin has 141 amino...Ch. 28 - Prob. 28.42P
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