The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn. Concept Introduction: The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

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Answer 1

Question

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

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Answer 3

Question

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

Answer 6

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3

Answer 7

Chapter 28, Problem 28.7P

Interpretation Introduction

Interpretation:

The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.

Concept Introduction:

The functional group ketone (keto group) will be in equilibrium with the enol (alcohol group) form which is said to be the keto-enol tautomerization. The keto form is more stable when compared to the enol form. The keto-enol conversion reaction is

Answer 8

Expert Solution & Answer

Explanation of Solution

The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.

The enethiol form of 6-mercaptopurine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 2

The enethiol form of 6-thioguanine is

Organic Chemistry, Chapter 28, Problem 28.7P , additional homework tip 3