The increasing order of reactivity toward nitration with HNO 3 of the compounds, thiophene, benzene, 3 − methylthiophene and 2 − methylfuran is to be stated with explanation. Concept introduction: Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound. Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π - bonds or by interaction of the lone pair of electrons and π - bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Answer 2

Question

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Answer 3

Question

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Answer 4

Question

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

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Answer 5

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 6

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 7

Chapter 26, Problem 26.28AP

Interpretation Introduction

Interpretation:

The increasing order of reactivity toward nitration with HNO3 of the compounds, thiophene, benzene, 3− methylthiophene and 2− methylfuran is to be stated with explanation.

Concept introduction:

Electrophilic substitution reactions are those reactions in which an electrophile replaces the atom or functional group of a compound.

Resonance is a phenomenon in which polarity is generated in a molecule by the interaction of the conjugated π- bonds or by interaction of the lone pair of electrons and π- bonds. In this phenomenon, the delocalization of the lone pair of electrons occurs. More the resonating structures of a compound, more stable is the compound.

Answer 8

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Answer 11

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains the increasing order of reactivity toward nitration with HNO_ 3 of the compounds.

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