(a) Interpretation: The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted. Concept introduction: Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group .

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Answer 1

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 2

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 3

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 4

Question

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

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Answer 5

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 6

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 7

Chapter 26, Problem 26.42AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanism for the reversible reaction of aryl-sulfonic acid in steam is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The identification of compound A, B and C in the given reaction scheme is to be predicted.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Sulfonation is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the sulfonic acid functional group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The explanation as to why compound C cannot be synthesized in one step from thiophene.

Concept introduction:

Electrophilic substitution reactions are that reaction in which an electrophile replaces the atom or function group of a compound. Nitration is an electrophilic substitution reaction in which the hydrogen atom of an aromatic ring is replaced by the nitro group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains the curved arrow mechanism for reversible reaction of aryl-sulfonic acid in steam.

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Chapter 26 Solutions