Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 25.6, Problem 23P
Interpretation Introduction

Interpretation:

The Wohl degradation in carbohydrates is a chain contraction method for aldoses.

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what is the structure digested by and how many reducing sugars are present ОН ОН Но OH HO Но HO- OH HO, The trisaccharide pictured could be completely digested (ie into monomers) by a beta-galactosidase and an alpha-glucosidase an alpha-galactosidase and sucrase lactase and sucrase a beta-fructosidase and lactase
A D-aldohexose A is formed from an aldopentose B by the Kiliani-Fischer synthesis. Reduction of A with NABH4 forms an optically inactive alditol. Oxidation of B forms an optically active aldaric acid. What are the structures of A and B?
Iis D-glucose capable of forming mutarotation in solid state?

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