Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 25, Problem 25.27AP
Interpretation Introduction

(a)

Interpretation:

The structure of more reactive enantiomer of sarin is to be drawn.

Concept introduction:

The phosphorous atom in the sarin is the chiral center having three different groups bonded to it. The stereochemistry of at the chiral center can be determined by assigning the priority to the groups attached according to the Cahn Ingold Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The product formed in the reaction of (S)-sarin with serine is to be determined.

Concept introduction:

The enzyme catalyzed substitution reaction of phosphate ester derivate at phosphate proceeds through SN2 reaction and results in inversion of stereochemistry.

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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless otherwise noted. a) &l BH3 •THF b) 1) NaOH 2) H3O+ solve d) ala 1) EtMgBr 2) H3O+ e) H2N سكر CuLi NH2 1) SOCI2 2) EtMgBr 3) H3O+ NC H3O+ Δ
There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:  QUESTION: Summarise and report these results including an indication of measurement uncertainty.  In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).   Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
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