To identify the number of ATP molecules needed when a glucose unit is added to a growing glycogen chain. Concept introduction: Glucose is a monosaccharide with the molecular formula C 6 H 12 O 6 . Glycogen is a polysaccharide of glucose. It serves as a form of carbohydrate storage in humans and animals. Glycogen is a source of glucose in humans and animals. Adenosine triphosphate (ATP) is the energy currency of life that provides energy to carry out the metabolic processes in the living cells. After the consumption in the metabolic processes, ATP is converted either to adenosine monophosphate (AMP) or to adenosine diphosphate (ADP). Glycogenesis is the metabolic pathway that converts glucose 6 − phosphate to glycogen.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Chapter 24.5, Problem 3QQ

Interpretation Introduction

Interpretation: To identify the number of ATP molecules needed when a glucose unit is added to a growing glycogen chain.

Concept introduction: Glucose is a monosaccharide with the molecular formula C6H12O6. Glycogen is a polysaccharide of glucose. It serves as a form of carbohydrate storage in humans and animals. Glycogen is a source of glucose in humans and animals.

Adenosine triphosphate (ATP) is the energy currency of life that provides energy to carry out the metabolic processes in the living cells. After the consumption in the metabolic processes, ATP is converted either to adenosine monophosphate (AMP) or to adenosine diphosphate (ADP).

Glycogenesis is the metabolic pathway that converts glucose 6−phosphate to glycogen.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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