The statement, “Electron-withdrawing property of 2, 4-dinitrophenyl group, which makes separation of the labeled amino acid very easy”, is to be explained. Concept introduction: The amino acids are polymerized by enzymes and form amide linkages. The amino acids are joined together to form a peptide. The amide linkages formed in them are called peptide bonds. The single amino acid is called amino acid residue. The determination of the sequence of amino acids in the polypeptide is by terminal residue analysis. This technique helps in identifying the N- and C-terminal amino acids.

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 24, Problem 5PP

Interpretation Introduction

Interpretation:

The statement, “Electron-withdrawing property of 2, 4-dinitrophenyl group, which makes separation of the labeled amino acid very easy”, is to be explained.

Concept introduction:

The amino acids are polymerized by enzymes and form amide linkages. The amino acids are joined together to form a peptide. The amide linkages formed in them are called peptide bonds. The single amino acid is called amino acid residue.

The determination of the sequence of amino acids in the polypeptide is by terminal residue analysis. This technique helps in identifying the N- and C-terminal amino acids.

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Draw zwitterion forms of these amino acids. (a) Valine (b) Phenylalanine (c) Glutamine

Draw the structure of the tetrapeptide Asp-Arg-Val-Tyr. Please show the appropriate stereochemistry of the natural amino acids in the resulting peptide. Please draw all ionizable groups in their neutral form.

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 24, Problem 5PP

Interpretation Introduction

Interpretation:

The statement, “Electron-withdrawing property of 2, 4-dinitrophenyl group, which makes separation of the labeled amino acid very easy”, is to be explained.

Concept introduction:

The amino acids are polymerized by enzymes and form amide linkages. The amino acids are joined together to form a peptide. The amide linkages formed in them are called peptide bonds. The single amino acid is called amino acid residue.

The determination of the sequence of amino acids in the polypeptide is by terminal residue analysis. This technique helps in identifying the N- and C-terminal amino acids.

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 24, Problem 5PP

Interpretation Introduction

Interpretation:

The statement, “Electron-withdrawing property of 2, 4-dinitrophenyl group, which makes separation of the labeled amino acid very easy”, is to be explained.

Concept introduction:

The amino acids are polymerized by enzymes and form amide linkages. The amino acids are joined together to form a peptide. The amide linkages formed in them are called peptide bonds. The single amino acid is called amino acid residue.

The determination of the sequence of amino acids in the polypeptide is by terminal residue analysis. This technique helps in identifying the N- and C-terminal amino acids.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 24, Problem 5PP

Interpretation Introduction