Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 24, Problem 21P
Interpretation Introduction

Interpretation:

The structural feature of polyglutamic acid and the chemical change for given transformation are to be explained.

Concept introduction:

The d-glutamic acid and l-glutamic acid monomers have to get polymerized to give polyglutamic acid (PGA). Bonds are formed between the α-amino and γ-carboxyl groups of the glutamic acids. The structure is shown in the figure. Interlinked amide linkages between the α-amino and γ-carboxyl groups constitute the structure of PGA.

Organic Chemistry, Chapter 24, Problem 21P

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option choice:  Isoleucine Histidine Threonine Alanine Lysine Aspartate Tryptophan Tyrosine Leucine Arginine Cysteine Asparagine Valine Glutamine Glycine Methionine Serine Proline Phenylalanine Glutamate
sketch the nature of the metal-alkylidene bonding interactions.
Part C The perspective formula of isoleucine, an amino acid, is provided below. HOOC H₂NIC H 川 CH3 CH,CH3 Draw the Newman projection in staggered conformation for isoleucine by viewing the molecule along the C-2-C-3 bond. 1. Edit the Newman projection on the canvas. 2. Replace the appropriate hydrogens with the appropriate -CH3 or other groups. 3. If you need to start over, Undo or choose a Newman projection from the Templates toolbar (bottom). Important: Never delete the hydrogen atoms or bonds directly attached to the template, and do not move them by dragging or dropping them. That will break the projections structures. Only replace them! ▸ View Available Hint(s) 0 2 H± 3D EXP. L ד י CONT. 2 H 0 N о
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