The structures of 2 - b u tan o l and its mirror image has to be drwan and both structures are superimposable or not has to be identified. Concept introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word. Prefix - Represents the substituent present in the molecule and its position in the root name. Suffix - Denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on Root word - Represents the longest continuous carbon skeleton of the organic molecule. A chiral carbon is the carbon atom which is substituted to four different groups. Due to presence of chiral carbon a molecule become chiral and it gives optical isomers also that is R and S isomers. For example, All the substituents are different hence it is a chiral carbon and so molecule.

Question

ii) Molecular ion peak :the peak corresponding to the intact molecule (with a positive charge) What would the base peak and Molecular ion peaks when isobutane is subjected to Mass spectrometry? Draw the structures and write the molecular weights of the fragments. Circle most stable cation a) tert-butyl cation b) Isopropyl cation c) Ethyl cation. d) Methyl cation 6. What does a loss of 15 represent in Mass spectrum? a fragment of the molecule with a mass of 15 atomic mass units has been lost during the ionization Process 7. Write the isotopes and their % abundance of isotopes of i) Cl

Answer 1

Question

Chapter 23, Problem 68GQ

Interpretation Introduction

Interpretation:

The structures of 2-butanol and its mirror image has to be drwan and both structures are superimposable or not has to be identified.

Concept introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

A chiral carbon is the carbon atom which is substituted to four different groups. Due to presence of chiral carbon a molecule become chiral and it gives optical isomers also that is R and S isomers. For example,

All the substituents are different hence it is a chiral carbon and so molecule.

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