The reagent and condition is to be proposed for step 1. Concept introduction: Friedal – Crafts alkylation (or acylation): Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

Question

Aktiv Learning App Cengage Digital Learning Part of Speech Table for Assign x o Mail-Karen Ento-Outlook * + app.aktiv.com Your Aktiv Learning trial expires on 02/06/25 at 01:15 PM Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 17 of 30 Drawing Arrows heat 4 O M B D 5x H H Und Settings H Done :0: H Jar

Answer 1

Question

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

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Aktiv Learning App Cengage Digital Learning Part of Speech Table for Assign x o Mail-Karen Ento-Outlook * + app.aktiv.com Your Aktiv Learning trial expires on 02/06/25 at 01:15 PM Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 17 of 30 Drawing Arrows heat 4 O M B D 5x H H Und Settings H Done :0: H Jar

Convert the following chairs into ring representations: a. Brz b.

Drawing Arrows 1 I I 1 heat 1 51 MO + Drag To Und Settings Done 0 0 Jan 31 3:5

Answer 2

Question

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

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Answer 3

Question

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

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Answer 4

Question

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

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Answer 5

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

Answer 6

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

Answer 7

Chapter 23, Problem 23.64P

(a)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 1.

Concept introduction:

Friedal – Crafts alkylation (or acylation):

Friedal – Crafts alkylation (or acylation) is one of the electrophilic substitution reaction. Alkyl halide or acyl halides reaction with benzene (or electron donating group present in the benzene ring) in the presence of anhydrous aluminum trichloride which gives the corresponding alkylated or acylated compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reductive amination is to be explained and the explanation has to be given for two step synthesis of amination is used rather than reductive amination.

Concept introduction:

Reductive amination reaction: Amination is the process by which an amine group is introduced into an organic molecule.

The conversion of Carbonyl group in to amine via imine intermediate is called reductive amination.

Answer 12

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

Answer 13

(D)

Interpretation Introduction

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.

Answer 14

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

Answer 15

(E)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Achiral:

A molecule is superimposable on its mirror image is called achiral molecule.

Answer 16

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Answer 27

Ch. 23.1 - Prob. 23.1P Ch. 23.2 - Prob. 23.2P Ch. 23.2 - Prob. 23.3P Ch. 23.2 - Prob. 23.4P Ch. 23.5 - Prob. 23.5P Ch. 23.5 - Prob. AQ Ch. 23.5 - What is the hybridization of the nitrogen in...Ch. 23.5 - Prob. CQ Ch. 23.5 - The pKas of the conjugate acids of aniline and...Ch. 23.5 - Prob. EQ

Interpretation: The reagent and condition is to be proposed for step 2 and step 3. Concept introduction: Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

Interpretation: The reagent and condition is to be proposed for step 4 and step 5. Concept introduction: Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Chapter 23 Solutions

Interpretation:

The reagent and condition is to be proposed for step 2 and step 3.

Concept introduction:

Oxime formation: Aldehyde or ketone is reaction with hydroxylamine and sodium methoxide which yields oxime

Interpretation:

The reagent and condition is to be proposed for step 4 and step 5.

Concept introduction:

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH₄ which provides alcohol.