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Concept explainers
(a)
Interpretation:
The
Concept Introduction:
Amide: One
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Hemiacetal is an organic compound with a general formula
Alcohol: It is an organic compound where it contains at least one
(b)
Interpretation:
Number of chiral centers are present in desosamine has to be determined. Number of possible stereoisomers for desosamine and the number of enantiomers possible has to be determined.
Concept Introduction:
Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.
Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.
Number of possible stereoisomers for a compound can be determined as,
Enantiomers: They are chiral molecules whose mirror images are not superimposable.
Number of possible enantiomers for a compound can be determined as,
(c)
Interpretation:
The alternative chair conformations for desosamine have to be drawn.
Concept Introduction:
Drawing Axial and Equatorial substituents:
Each carbon in cyclohexane can bear two substituents. One group is said to occupy an axial position, which is parallel to a vertical axis passing through the center of the ring. The other group is said to occupy an equatorial position, which is positioned approximately along the equator of the ring.
(c)
Interpretation:
More stable alternative chair conformations for desosamine have to be identified and explained.
Concept Introduction:
Drawing Axial and Equatorial substituents:
Each carbon in cyclohexane can bear two substituents. One group is said to occupy an axial position, which is parallel to a vertical axis passing through the center of the ring. The other group is said to occupy an equatorial position, which is positioned approximately along the equator of the ring.
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Chapter 23 Solutions
Organic Chemistry
- Predict the major products of this organic reaction. If there will be no major products, check the box under the drawing area instead. No reaction. : + Х è OH K Cr O 2 27 2 4' 2 Click and drag to start drawing a structure.arrow_forwardLaminar compounds are characterized by havinga) a high value of the internal surface of the solid.b) a high adsorption potential.arrow_forwardIntercalation compounds have their sheetsa) negatively charged.b) positively charged.arrow_forward
- Indicate whether the following two statements are correct or not:- Polythiazine, formed by N and S, does not conduct electricity- Carbon can have a specific surface area of 3000 m2/garrow_forwardIndicate whether the following two statements are correct or not:- The S8 heterocycle is the origin of a family of compounds- Most of the elements that give rise to stable heterocycles belong to group d.arrow_forwardcould someone draw curly arrow mechanism for this question pleasearrow_forward
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