Nitrogen atom that is a more basic among the two nitrogen atoms present in epibatidine has to be explained. Concept introduction: Amines are the derivatives of ammonia ( N H 3 ) with one or more of the hydrogens replaced with a substituent such as an alkyl group. Depending on the number of carbon side chain of the nitrogen, different types of amines can form. According to the explanations by Lewis, if a species donates an electron pair then it is a Lewis base whereas if a species receives an electron pair, then it is Lewis acid. Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

Question

Draw all 8 stereoisomers, circling each pair of enantiomer(s)/ mirror image compound(s)

Answer 1

Question

Chapter 23, Problem 23.28P

(a)

Interpretation Introduction

Interpretation:

Nitrogen atom that is a more basic among the two nitrogen atoms present in epibatidine has to be explained.

Concept introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

According to the explanations by Lewis, if a species donates an electron pair then it is a Lewis base whereas if a species receives an electron pair, then it is Lewis acid.

Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

(b)

Interpretation Introduction

Interpretation:

Chiral centers in epibatidine have to be marked.

Concept Introduction:

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

Chirality: It refers to an atom in a molecule that contains four different substituents.

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Draw all 8 stereoisomers, circling each pair of enantiomer(s)/ mirror image compound(s)

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Deducing the reactants of a Diels-Alder reaction n the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ • If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. • If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. >