Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
Question
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Chapter 22.SE, Problem 23MP
Interpretation Introduction

a)

Organic Chemistry, Chapter 22.SE, Problem 23MP , additional homework tip  1

Interpretation:

Whether the ketone obtained by the decarboxylation of the optically active β- keto acid will be optically active or not is to be stated. A mechanism to explain the formation of the ketone is to be proposed.

Concept introduction:

The decarboxylation of a β- keto acid takes place through the formation of a planar enol intermediate which then tautomerizes to the keto form. If the β- keto acid is optically active and if the chiral centre is involved in the reaction, the ketone product will be racemic and optically inactive. If the chiral centre is not involved in the reaction then the optical activity is retained in the ketone product.

To state:

Whether the ketone obtained by the decarboxylation of the optically active β- keto acid will be optically active or not.

To propose:

A mechanism to explain the formation of the ketone.

Interpretation Introduction

b)

Organic Chemistry, Chapter 22.SE, Problem 23MP , additional homework tip  2

Interpretation:

Whether the ketone obtained by the decarboxylation of the optically active β- keto acid will be optically active or not is to be stated. A mechanism to explain the formation of the ketone is to be proposed.

Concept introduction:

The decarboxylation of a β- keto acid takes place through the formation of a planar enol intermediate which then tautomerizes to the keto form. If the β- keto acid is optically active and if the chiral centre is involved in the reaction, the ketone product will be racemic and optically inactive. If the chiral centre is not involved in the reaction then the optical activity is retained in the ketone product.

To state:

Whether the ketone obtained by the decarboxylation of the optically active β- keto acid will be optically active or not.

To propose:

A mechanism to explain the formation of the ketone.

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Chapter 22 Solutions

Organic Chemistry

Ch. 22.7 - Draw a resonance structure of the acetonitrile...Ch. 22.7 - Why do you suppose ketone halogenations in acidic...Ch. 22.7 - Prob. 13PCh. 22.7 - Prob. 14PCh. 22.7 - Prob. 15PCh. 22.7 - Prob. 16PCh. 22.SE - Prob. 17VCCh. 22.SE - Prob. 18VCCh. 22.SE - Prob. 19VCCh. 22.SE - Prob. 20MPCh. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Prob. 23MPCh. 22.SE - In the Hell–Volhard–Zelinskii reaction, only a...Ch. 22.SE - Prob. 25MPCh. 22.SE - Nonconjugated , -unsaturated ketones, such as...Ch. 22.SE - Prob. 27MPCh. 22.SE - Using curved arrows, propose a mechanism for the...Ch. 22.SE - Prob. 29MPCh. 22.SE - One of the later steps in glucose biosynthesis is...Ch. 22.SE - The Favorskii reaction involves treatment of an...Ch. 22.SE - Treatment of a cyclic ketone with diazomethane is...Ch. 22.SE - Prob. 33MPCh. 22.SE - Amino acids can be prepared by reaction of alkyl...Ch. 22.SE - Amino acids can also be prepared by a two-step...Ch. 22.SE - Heating carvone with aqueous sulfuric acid...Ch. 22.SE - Identify all the acidic hydrogens (pKa 25) in the...Ch. 22.SE - Rank the following compounds in order of...Ch. 22.SE - Prob. 39APCh. 22.SE - Base treatment of the following , -unsaturated...Ch. 22.SE - Prob. 41APCh. 22.SE - Prob. 42APCh. 22.SE - Prob. 43APCh. 22.SE - Which, if any, of the following compounds can be...Ch. 22.SE - Prob. 45APCh. 22.SE - Prob. 46APCh. 22.SE - Prob. 47APCh. 22.SE - How might you convert geraniol into either ethyl...Ch. 22.SE - Prob. 49APCh. 22.SE - One way to determine the number of acidic...Ch. 22.SE - Prob. 51APCh. 22.SE - Prob. 52APCh. 22.SE - Prob. 53APCh. 22.SE - Prob. 54APCh. 22.SE - Prob. 55APCh. 22.SE - Prob. 56APCh. 22.SE - All attempts to isolate primary and secondary...Ch. 22.SE - How would you synthesize the following compounds...Ch. 22.SE - Prob. 59APCh. 22.SE - Prob. 60APCh. 22.SE - Prob. 61APCh. 22.SE - Prob. 62APCh. 22.SE - As far back as the 16th century, South American...Ch. 22.SE - The key step in a reported laboratory synthesis of...Ch. 22.SE - Prob. 65AP
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