a) Interpretation: The enol tautomer of Cyclopentanone shown is to be given. Concept introduction: A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers. To give: The enol tautomer of cyclopentanone shown.

Question

Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false

Answer 1

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Indicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are false

(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 3

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 4

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 5

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 6

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Answer 7

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Answer 14

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Answer 15

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Answer 16

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 17

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 18

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Answer 29

Ch. 22.1 - Prob. 1P Ch. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3P Ch. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5P Ch. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7P Ch. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P

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