General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 22.1, Problem 22.5P
Label each statement about the compound deoxycytidine as true or false.
- Deoxycytidine is a
nucleotide . - Deoxycytidine is a nucleoside.
- Deoxycytidine contains a phosphate at its 5-OH group.
- Deoxycytidine contains a pyrimidine base.
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Q2. Consider the hydrogenation of ethylene
C2H4 + H2 = C2H6
The heats of combustion and molar entropies for the three gases at 298 K are given by:
C2H4
C2H6
H2
AH comb/kJ mol¹
-1395
-1550
-243
Sº / J K¹ mol-1
220.7
230.4
131.1
The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is
10.9 J K¹ mol¹. Using these data, determine:
(a) the standard enthalpy change at 800 K
(b) the standard entropy change at 800 K
(c) the equilibrium constant at 800 K.
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
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c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
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radical. Written explanation can be no more than one-two succinct sentence(s)!
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Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
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product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
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Product
6
Number of Unique
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b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
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H
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Chapter 22 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 22.1 - Prob. 22.1PPCh. 22.1 - Prob. 22.1PCh. 22.1 - -Fluorouracil is an anticancer drug that...Ch. 22.1 - Prob. 22.3PCh. 22.1 - Prob. 22.4PCh. 22.1 - Label each statement about the compound...Ch. 22.1 - Draw the structure of each nucleotide: (a) UMP;...Ch. 22.1 - Give the name that corresponds to each...Ch. 22.2 - Draw the structure of a dinucleotide formed by...Ch. 22.2 - Draw the structure of each polynucleotide: (a) CU;...
Ch. 22.2 - Label each statement about the polynucleotide...Ch. 22.3 - Write the complementary strand for each of the...Ch. 22.4 - What is the sequence of a newly synthesized DNA...Ch. 22.6 - For each DNA segment: [1] What is the sequence of...Ch. 22.6 - Prob. 22.9PCh. 22.7 - What amino acid is coded for by each codon? GCC...Ch. 22.7 - What codons code for each amino acid? a. glycine...Ch. 22.7 - Drive the amino acid sequence that is coded for by...Ch. 22.7 - Write a possible mRNA sequence that codes for each...Ch. 22.7 - Considering the given sequence of nucleotides in...Ch. 22.8 - Prob. 22.14PCh. 22.8 - Prob. 22.8PPCh. 22.8 - Prob. 22.9PPCh. 22.9 - Prob. 22.10PPCh. 22.9 - Prob. 22.15PCh. 22.10 - Prob. 22.16PCh. 22 - Label each statement as pertaining to DNA, RNA, or...Ch. 22 - Label each statement as pertaining to DNA, RNA, or...Ch. 22 - Prob. 19PCh. 22 - (a) Give the name of each compound shown as a...Ch. 22 - Prob. 21PCh. 22 - Prob. 22PCh. 22 - Prob. 23PCh. 22 - Prob. 24PCh. 22 - Prob. 25PCh. 22 - Draw the structure of each of the following: a...Ch. 22 - Prob. 27PCh. 22 - Prob. 28PCh. 22 - Prob. 29PCh. 22 - Prob. 30PCh. 22 - Prob. 31PCh. 22 - Draw the structures of the two possible...Ch. 22 - Prob. 33PCh. 22 - Draw the structure of each dinucleotide and...Ch. 22 - Draw the deoxyribonucleotide TGA. Label the 5 and...Ch. 22 - Draw the ribonucleotide CGU. Label the 5 and 3...Ch. 22 - Prob. 37PCh. 22 - Describe in detail the DNA double helix with...Ch. 22 - Write the sequence of the complementary strand of...Ch. 22 - Prob. 40PCh. 22 - Prob. 41PCh. 22 - Prob. 42PCh. 22 - Prob. 43PCh. 22 - Prob. 44PCh. 22 - Prob. 45PCh. 22 - Figure 22.4 snows the hydrogen-bonding...Ch. 22 - Prob. 47PCh. 22 - Prob. 48PCh. 22 - Prob. 49PCh. 22 - Prob. 50PCh. 22 - What mRNA is transcribed from each DNA sequence in...Ch. 22 - Prob. 52PCh. 22 - For each DNA segment: [1] What is the sequence of...Ch. 22 - Prob. 54PCh. 22 - For each codon, give its anticodon and the amino...Ch. 22 - For each codon, give its anticodon and the amino...Ch. 22 - Fill in the missing information in the schematic...Ch. 22 - Fill in the missing information in the schematic...Ch. 22 - Derive the amino acid sequence that is coded for...Ch. 22 - Derive the amino acid sequence that is coded for...Ch. 22 - Write a possible mRNA sequence that codes for each...Ch. 22 - Prob. 62PCh. 22 - Prob. 63PCh. 22 - Prob. 64PCh. 22 - Prob. 65PCh. 22 - Prob. 66PCh. 22 - Consider the following mRNA sequence:...Ch. 22 - Consider the following mRNA sequence: 5-ACC UUA...Ch. 22 - Consider the following sequence of DNA: 3-TTA...Ch. 22 - Consider the following sequence of DNA: 3-ATA...Ch. 22 - Prob. 71PCh. 22 - Prob. 72PCh. 22 - Prob. 73PCh. 22 - Prob. 74PCh. 22 - Prob. 75PCh. 22 - Prob. 76PCh. 22 - Prob. 77PCh. 22 - Prob. 78PCh. 22 - Prob. 79PCh. 22 - Prob. 80PCh. 22 - Prob. 81PCh. 22 - Prob. 82PCh. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Prob. 86PCh. 22 - Prob. 87PCh. 22 - Prob. 88PCh. 22 - Prob. 89PCh. 22 - Prob. 90PCh. 22 - Prob. 91CPCh. 22 - Give a possible nucleotide sequence in the...
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