Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 22, Problem 68P
Interpretation Introduction
Interpretation:
The enzyme which is monitored in the diagnosis of infectious hepatitis is to be predicted.
Concept Introduction:
Hepatitis is medical condition related to the inflammation of liver. Enzymes are the
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In the table below, the exact chemical structures for Methyl salicylate can be
represented by the letter
WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR
PHRASES
CI
B)
A)
E)
Cl
racemic
F)
J)
CI
K)
N)
OH
P)
Pool of Reagents for Part B
OH
OH
G)
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OH
D)
HO
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M)
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
Chapter 22 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 22.1 - Prob. 22.1QCCh. 22.2 - Prob. 22.2QCCh. 22.3 - Prob. 22.3QCCh. 22.4 - Which of the following is true regarding enzymes?...Ch. 22.5 - Match the description of the enzyme process with...Ch. 22 - What is the difference between a catalyst and an...Ch. 22 - What are ribozymes made of?Ch. 22 - Would a lipase hydrolyze two triglycerides, one...Ch. 22 - Compare the activation energy in uncatalyzed...Ch. 22 - Prob. 5P
Ch. 22 - Prob. 6PCh. 22 - Prob. 7PCh. 22 - Monoamine oxidases are important enzymes in brain...Ch. 22 - Prob. 9PCh. 22 - 0 What kind of reaction does each of the following...Ch. 22 - Prob. 11PCh. 22 - In most enzyme-catalyzed reactions, the rate of...Ch. 22 - 5 At a very low concentration of a certain...Ch. 22 - 6 If we wish to double the rate of an...Ch. 22 - 7 A bacterial enzyme has the following...Ch. 22 - 8 The optimal temperature for the action of...Ch. 22 - 9 The activity of pepsin was measured at various...Ch. 22 - Prob. 18PCh. 22 - Prob. 19PCh. 22 - Prob. 20PCh. 22 - Prob. 21PCh. 22 - 4 What kind of chemical reaction occurs most...Ch. 22 - 5 Which of the following is a correct statement...Ch. 22 - Prob. 24PCh. 22 - 7 Enzymes are long protein chains, usually...Ch. 22 - Prob. 26PCh. 22 - Prob. 27PCh. 22 - 0 Can the product of a reaction that is part of a...Ch. 22 - 1 What is the difference between a zymogen and a...Ch. 22 - 2 The enzyme trypsin is synthesized by the body in...Ch. 22 - Prob. 31PCh. 22 - Prob. 32PCh. 22 - Prob. 33PCh. 22 - Prob. 34PCh. 22 - Prob. 35PCh. 22 - Prob. 36PCh. 22 - Prob. 37PCh. 22 - Prob. 38PCh. 22 - 1 After a heart attack, the levels of certain...Ch. 22 - Prob. 40PCh. 22 - Prob. 41PCh. 22 - Prob. 42PCh. 22 - 5 Chemists who have been exposed for years to or...Ch. 22 - 6 Which enzyme preparation is given to patients...Ch. 22 - 7 Chymotrypsm is secreted by the pancreas and...Ch. 22 - Prob. 46PCh. 22 - Prob. 47PCh. 22 - Prob. 48PCh. 22 - Prob. 49PCh. 22 - Prob. 50PCh. 22 - Prob. 51PCh. 22 - Prob. 52PCh. 22 - Prob. 53PCh. 22 - Prob. 54PCh. 22 - Prob. 55PCh. 22 - Prob. 56PCh. 22 - Prob. 57PCh. 22 - Prob. 58PCh. 22 - Prob. 59PCh. 22 - Prob. 60PCh. 22 - 1 Food can be preserved by inactivation of enzymes...Ch. 22 - Prob. 62PCh. 22 - 3 Would you expect to find active digestive...Ch. 22 - Prob. 64PCh. 22 - Prob. 65PCh. 22 - Prob. 66PCh. 22 - 7 An enzyme has the following pH dependence: At...Ch. 22 - Prob. 68PCh. 22 - Prob. 69PCh. 22 - 0 Nerve gases operate by forming covalent bonds at...Ch. 22 - 1 What would be the appropriate name for an enzyme...Ch. 22 - Prob. 72PCh. 22 - 3 A liver enzyme is made of four subunits: 2A and...Ch. 22 - Prob. 74PCh. 22 - Prob. 75PCh. 22 - Prob. 76PCh. 22 - Prob. 77PCh. 22 - Prob. 78PCh. 22 - Prob. 79PCh. 22 - Prob. 80PCh. 22 - Prob. 81P
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- 3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forward
- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
- What are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forward
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