
Concept explainers
Interpretation:
The major product of the given reaction sequenceis to be determined.
Concept Introduction:
Reaction of an aldehyde or a ketone with a secondary
If the aldehyde or ketone is unsymmetrical, then a mixture of two enamines is obtained.
In this mixture of enamines, the one with the less substituted double bond predominates.
Enamines are nucleophilic and react with electrophiles forming a new carbon-carbon bond. Further, hydrolysis produces a derivative of the original aldehyde or ketone such that the substituent is attached to the alpha position.
Primary

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Chapter 22 Solutions
Organic Chemistry - Standalone book
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