Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained. Concept Introduction: > The major factors that contribute to the basic strength are s character, inductive effect and polarity. > The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds. > An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton. > The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

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Answer 1

Question

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

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Answer 2

Question

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Answer 6

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Answer 7

Chapter 22.4, Problem 7P

Interpretation Introduction

Interpretation:

Considering the resonance structure, the reason that the given compounds are weaker base than aniline corresponding to the effect of the substituent is to be explained.

Concept Introduction:
>
The major factors that contribute to the basic strength are s character, inductive effect and polarity.
>
The high percentage of s character decreases the basicity, Positive inductive effect increases the basic strength of the compounds, whilenegative inductive effect decreases the basic strength of the compounds.
>
An acidic substance in a reaction donates a proton, while a base in a reaction accepts a proton.
>
The elimination of a proton leads to the formation of a conjugate base. If the base accepts a proton the species formed is known as conjugate acid.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Prob. 3P Ch. 22.2 - Prob. 4P Ch. 22.4 - Prob. 5P Ch. 22.4 - Prob. 6P Ch. 22.4 - Prob. 7P Ch. 22.4 - Prob. 8P Ch. 22.4 - Prob. 9P Ch. 22.7 - Prob. 10P

Solution Summary: The author explains the resonance structure of o- Cyanoaniline and p- Aminoacetophenone.

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Chapter 22 Solutions