The given compounds are to be ranked in decreasing order of basicity. Concept Introduction: The p K a value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity. The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

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Answer 1

Question

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

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Select the stronger base from each pair of compounds. (a) H₂CNH₂ or EtzN (b) CI or NH2 NH2 (c) .Q or EtzN (d) or (e) N or (f) H or H

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b. H3C CH3 H3O+ ✓ H OH

Answer 2

Question

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

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Answer 3

Question

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

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Answer 4

Question

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

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Answer 5

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

Answer 6

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

Answer 7

Chapter 22, Problem 29P

Interpretation Introduction

Interpretation:

The given compounds are to be ranked in decreasing order of basicity.

Concept Introduction:

The pKa value is directly related to the basic strength of the compound. The major factors that contribute to the basic strength are s character, inductive effect and polarity.

The high percentage of s character decreases the basicity. There are two types of inductive effects named as positive and negative inductive effect. Positive inductive effect increases the basic strength of the compounds, whereas negative inductive effect decreases the basic strength of the compounds.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Prob. 3P Ch. 22.2 - Prob. 4P Ch. 22.4 - Prob. 5P Ch. 22.4 - Prob. 6P Ch. 22.4 - Prob. 7P Ch. 22.4 - Prob. 8P Ch. 22.4 - Prob. 9P Ch. 22.7 - Prob. 10P

Solution Summary: The author explains that the basicity of the compounds depends on the groups attached to the functional groups.

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Chapter 22 Solutions