Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 22, Problem 61DSP
Interpretation Introduction

Interpretation:

The product of the given reaction sequenceis to be determined

Concept Introduction:

Reaction of an aldehyde or a ketone with a secondary amine gives an enamine.

Enamines are nucleophilic and react with electrophiles forming a new carbon-carbon bond. Further hydrolysis produces a derivative of the original aldehyde or ketone such that the substituent is attached to the alpha position.

Enamines react with α,β-unsaturated ketones to produce alpha substituted derivatives of aldehydes or ketones.

The intramolecular Aldol condensation reaction can take place when there is a possibility of formation of a five or six membered ring.

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