The reason for colorless nature of the complex ion [ Z n ( H 2 O ) 4 ] 2 + has to be explained. Concept Introduction: Co-ordination compounds are primarily formed by transition elements which are d-block elements. A co-ordination compound is known as a complex compound is made of metal atom/ion and ligand(s). Ligands are considered as Lewis bases and the central metal atom is Lewis acid. Ligands donate a pair of electron to metal ion and establish bonding with metal ion which is known as co-ordinate bond and hence these compounds are named as co-ordination compounds. The ligands represented inside the square brackets adjacent to the central metal ion, which is termed as co-ordination sphere. Many of the complex compounds are due to the presence of unpaired electrons in d-orbital of metal ion and exchange of energy between them.

Question

10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation → depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O II HA H CH3O-H H ①

Answer 1

Question

Chapter 22, Problem 22.68QP

Interpretation Introduction

Interpretation:

The reason for colorless nature of the complex ion [Zn(H2O)4]2+ has to be explained.

Concept Introduction:

Co-ordination compounds are primarily formed by transition elements which are d-block elements. A co-ordination compound is known as a complex compound is made of metal atom/ion and ligand(s). Ligands are considered as Lewis bases and the central metal atom is Lewis acid. Ligands donate a pair of electron to metal ion and establish bonding with metal ion which is known as co-ordinate bond and hence these compounds are named as co-ordination compounds. The ligands represented inside the square brackets adjacent to the central metal ion, which is termed as co-ordination sphere.

Many of the complex compounds are due to the presence of unpaired electrons in d-orbital of metal ion and exchange of energy between them.

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10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation → depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O II HA H CH3O-H H ①

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