Structure of cis-trans isomer of the following complexes has to be drawn. (a) [ C o ( N O 2 ) 4 ( N H 3 ) 2 ] − (b) [ C o ( N H 3 ) 5 ( N O ) 2 ] 2 + (c) [ C o ( N H 3 ) 6 ] 3 + (d) [ C r ( N H 3 ) 5 C l ] 2 + Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 1

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 2

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 3

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 4

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 5

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 6

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 7

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains the structure of cis-trans isomer of the following complexes.

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Chapter 22 Solutions