Bundle: General Chemistry, Loose-Leaf Version, 11th + LabSkills PreLabs v2 for Organic Chemistry (powered by OWLv2), 4 terms (24 months) Printed ... for Ebbing/Gammon's General Chemistry, 11th
11th Edition
ISBN: 9781337542630
Author: Darrell Ebbing, Steven D. Gammon
Publisher: Cengage Learning
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Chapter 22, Problem 22.16QP
Interpretation Introduction
Interpretation:
The following terms – Geometric isomerism and optical isomerism have to be defined and an example for each term has to be given.
Concept Introduction:
Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 22 Solutions
Bundle: General Chemistry, Loose-Leaf Version, 11th + LabSkills PreLabs v2 for Organic Chemistry (powered by OWLv2), 4 terms (24 months) Printed ... for Ebbing/Gammon's General Chemistry, 11th
Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1ECh. 22.4 - Prob. 22.2ECh. 22.5 - Prob. 22.2CCCh. 22.5 - Prob. 22.3ECh. 22.5 - Prob. 22.4ECh. 22.5 - Prob. 22.3CCCh. 22.7 - Prob. 22.5ECh. 22.7 - Prob. 22.6ECh. 22.7 - Prob. 22.7E
Ch. 22 - What characteristics of the transition elements...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Prob. 22.4QPCh. 22 - Prob. 22.5QPCh. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Silver(I) ion in basic solution is reduced by...Ch. 22 - What evidence did Werner obtain to show that the...Ch. 22 - Define the terms complex ion, ligand, and...Ch. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - Prob. 22.14QPCh. 22 - Prob. 22.15QPCh. 22 - Prob. 22.16QPCh. 22 - Explain the difference in behavior of d and l...Ch. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - a Describe the steps in the formation of a...Ch. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Prob. 22.26QPCh. 22 - Prob. 22.27QPCh. 22 - Prob. 22.28QPCh. 22 - What is the correct name for the coordination...Ch. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - Prob. 22.33QPCh. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - Prob. 22.41QPCh. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Consider the complex ion [CoCl(en)2(NO2)]+. a What...Ch. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Name the following complexes, using IUPAC rules. a...Ch. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Give the structural formula for each of the...Ch. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - Prob. 22.55QPCh. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Prob. 22.62QPCh. 22 - Prob. 22.63QPCh. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - There are only two geometric isomers of the...Ch. 22 - Prob. 22.70QPCh. 22 - Prob. 22.71QPCh. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Consider the complex ion [CoCO3(NH3)4], where the...Ch. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QPCh. 22 - Prob. 22.81QPCh. 22 - Prob. 22.82QPCh. 22 - What is the name of K2[MoOCl4]?Ch. 22 - Write the formula and draw the structure of...Ch. 22 - Prob. 22.85QPCh. 22 - Prob. 22.86QPCh. 22 - Is it possible to have a paramagnetic...Ch. 22 - Prob. 22.88QPCh. 22 - Prob. 22.89QPCh. 22 - Prob. 22.90QPCh. 22 - Prob. 22.91QPCh. 22 - Prob. 22.92QP
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